《V_2O_5_TiO_2_ZrO_2催化剂上甲醇选择氧化制甲缩醛》.pdf

39 1 Vol. 39 No. 1 2011 1 Journalof FuelChe istry and Technology Jan. 2011 : 2011) V O /T iO ZrO 2 5 2 2 1, 2 1 1 1, 2 1, 2 1, 2 1 武建兵 , 王 辉 , 秦张峰 , 吴志伟 , 黄礼春 , 赵 启 , 王建国 ( 1. , 030001; 2. , 100049) : T iO ZrO V O /T iO Z rO , 2 2 2 5 2 2 (DMM ), T iO Z rO , V O / 2 2 2 5 T iO ZrO XRDNH TPD H TPR, Z rO 2 2 3 2 2 ,, ,; V O 5% ~ 10% 2 5 : ; ; ; V O ; T iO ; Z rO 2 5 2 2 : O643. 3; TQ519 : A Selective ox idation of m ethanol to d im ethoxym ethane over V O /T iO Z rO ca ta lyst 2 5 2 2 1, 2 1 1 WU Jianbing , WANG Hui, QIN Zhangfeng, 1, 2 1, 2 1, 2 1 WU Zhiw ei , HUANG Lichun , ZHAO Q i , WANG Jianguo ( 1. StateK ey Laboratory of Coal Conversion, Institute of Coal Chem istry, ChineseA cademy of Sciences, Taiyuan 030001, China; 2. Graduate University of ChineseAcademy of Sciences, eijing 100049, China) A bstract: The co positeTiO ZrO supportw as prepared through coprecipitation of Ti( SO ) andZr( SO ) 2 2 4 2