Sn_O_H_N_C_Cl系统中锡的氧化动力学研究.pdfVIP

26 卷 18 期 中 国 电 机 工 程 学 报 Vol.26 No.18 Sep. 2006 2006 年9 月 Proceedings of the CSEE 2006 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2006) 18-0106-05 中图分类号：TM921 文献标识码：A 学科分类号：47020 Sn/O/H/N/C/Cl 系统中锡的氧化动力学研究 瑜，徐明厚，王 臣 (华中科技大学煤燃烧国家重点实验室，湖北省 武汉市 430074) The Oxidation Kinetics of Tin in Sn/O/H/N/C/Cl System QIAO Yu, XU Ming-hou,WANG Chen (National Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, Hubei Proveince, China) ABSTRACT: The potential for regulation of tin emissions 化动力学模型。在典型的反应温度和组分浓度下进行了动力 from coal-fired boilers is a concern for the electric utility 学的数值模拟，并通过敏感性分析找到了影响系统反应速率 industry. Field data show a wide variation in the fraction of tin 最重要的基元反应。 that is emitted as a vapor vs. that retained in the solid products. 关键词：煤燃烧；锡；化学反应动力学；Sn/O/H/N/C/Cl 系 The reason for this variation is not well understood. Near the 统 end of the flue gas path, tin exists as a combination of 0 引言 elemental vapor and SnO vapor. The data show that soluble SnO is more likely to be removed from the flue gas. So the 人类对锡的利用可以追溯到青铜时代，一直以 chemical kinetic mechanisms of tin are needed to describe 来，锡被认为是无害的。自20 世 80 年代以来， accurately tin reaction products and their concentrations-time 世界锡的生产和消耗已远超过自然风化量，并在大 correlation. It is necessary to develop tin chemical kinetics for 气中高倍量富集，引起环境学界的关注。80 年代后， application to real combustion system. Based on quantum 各国相继发现有机锡化合物尤其是三苯