典型煤种加压热解与气化实验研究.pdfVIP

第 27 卷 第 26 期 中 国 电 机 工 程 学 报 Vol.27 No.26 Sep. 2007 2007 年 9 月 Proceedings of the CSEE ©2007 Chin.Soc.for Elec.Eng. 0258-8013 (2007) 26-0018-05 TK224 A 470 20 文章编号： 中图分类号： 文献标识码： 学科分类号： ⋅ 典型煤种加压热解与气化实验研究 杨海平，陈汉平，鞠付栋，王 静，张世红 (华中科技大学煤燃烧国家重点实验室，湖北省 武汉市 430074) Study on Pressurized Pyrolysis and Gasification of Chinese Typical Coal Samples YANG Hai-ping, CHEN Han-ping, JU Fu-dong, WANG Jing, ZHANG Shi-hong (State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, Hubei Province, China) ABSTRACT: To understand the influence of pressure on the 本，煤的气化反应性很大程度上取决于煤的热解过 pyrolysis characteristics and the gasification reactivity of the 程[2-5] 。煤焦的气化活性不仅受煤种的影响，而且还 resultant solid coal char, the pyrolysis of 4 typical Chinese coals 与运行压力、终温及停留时间等操作条件有关[4-13] 。 samples were carried out at ambient pressure and 3Mpa using pressurized thermogravimetric analyzer, and the pore structure Kajitani和Ahn等研究发现增加气化压力促进了气化 characteristics and elemental components of the resultant char 反应的进行，煤焦的表面反应及孔内部气体扩散是 were measured. Simultaneously, the isothermal gasification 控制气化反应的主要因素[14-15] 。Wall等人发现气化 behavior of solid char particles was investigated using ambient 压力对挥发分的析出和煤焦的膨化有显著影响，从 thermal analyzer with CO2 as gasifying agent. It can be 而影响煤焦的表面孔隙结构，而煤焦结构特性对其 observed the pyrolysis of coal particles was suppressed with pyrolysis pressure increasing from ambient to 3Mpa, and the 气化速率和灰的形成有重要影响[9,16] 。Messenböck solid charcoal yield was enhanced. H content of the resultant 等研究发现随热解与气化压力的增大，煤焦的燃烧 charcoal decreased while C conte