可再生乙二胺湿法烟气脱硫实验研究.pdfVIP

第 29 卷 第 29 期 中 国 电 机 工 程 学 报 Vol.29 No.29 Oct. 15, 2009 2009 年 10 月 15 日 Proceedings of the CSEE ©2009 Chin.Soc.for Elec.Eng. 57 0258-8013 (2009) 29-0057-05 X 511 文献标志码：A 学科分类号：470·20 文章编号： 中图分类号： 可再生乙二胺湿法烟气脱硫实验研究 翟林智，钟秦，王娟 (南京理工大学化工系，江苏省 南京市 210094) Experimental Study on the Regenerable Wet Flue Gas Desulfurization With Ethylenediamine ZHAI Lin-zhi, ZHONG Qin, WANG Juan (School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu Province, China) ABSTRACT: Boric acid, phosphate acid, citric acid, and 响。确定吸收SO 适宜的工艺条件：吸收剂温度 30 ℃，乙二 2 sulfuric acid as additives, a series of ethylenediamine-based 胺浓度 0.3 mol/L ，吸收剂pH为 8.5。结果显示，实验范围内， desulfurizers were prepared. SO2 absorption capacity and 烟气中SO2浓度越大，脱硫率越高。 removal efficiency were studied. The results show that 关键词：烟气脱硫；乙二胺；乙二胺/硼酸；脱硫率 absorption capacity of SO2 in ethylenediamine/boric acid solvent is 450 mg/L, and the desulfurization efficiency reaches 0 引言 to 97%. The cycles of ethylenediamine/boric acid solvent were 与传统的石灰石/石膏湿法[1-6]烟气脱硫和活性 also performed for ten times. The desulfurization efficiency reaches above 99% and pH value of the solvent are stable at 焦干法[7-11]烟气脱硫相比，可再生胺法[12-13]因其具有 6.10~6.23. Ethylenediamine/boric acid solvent was selected as 副产物污染小、吸收胺液可循环使用、硫资源可合 a better absorbent to study the wet flue gas desulphurization 理利用和能耗少等优点成