以煤为燃料的化学链燃烧的研究进展.pdfVIP

第34 卷 第29 期 中 国 电 机 工 程 学 报 Vol.34 No.29 Oct.15, 2014 2014 年10 月15 日 Proceedings of the CSEE ©2014 Chin.Soc.for Elec.Eng. 5131 DOI ：10.13334/j.0258-8013.pcsee.2014.29.015 文章编号：0258-8013 (2014) 29-5131-09 中图分类号：TK 123 以煤为燃料的化学链燃烧研究进展 李振山，鲍金花，孙宏明，徐雷，蔡宁生 (清华大学科学与动力工程教育部重点实验室，北京市 海淀区 100084) Research and Development of Coal-fueled Chemical Looping Combustion LI Zhenshan, BAO Jinhua, SUN Hongming, XU Lei, CAI Ningsheng (Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Tsinghua University, Haidian District, Beijing 100084, China) ABSTRACT: Coal-fueled chemical looping combustion was 光滑的Fe 多晶片作为反应物，借助扫描电镜观测固体产物， studied from three aspects. In the aspect of oxygen carriers, the 剥离了孔隙结构的影响，解决固体产物微观形貌难以直接观 gas-solid reaction of carriers was studied. Multi-crystal Fe with 察的问题；建立了基于分子尺度固体产物成核与生长的速率 smooth surface was used as the reactant to eliminate the effect 方程，从微观分子尺度来描述宏观的动力学行为；建立活性 of pore structure. The morphology of solid products was 成分与惰性载体间相互作用力模型；提出通过引入外来离子 observed under a scanning electron microscope. The problem 提高天然钛铁矿载氧体反应活性的方法。在煤与载氧体相互 of directly observing the product morphology was solved. A 作用方面，考虑了挥发分、煤灰对载氧体的影响；采用催化 rate equation theory was developed to describe the 气化使气化速率与还原速率相匹配；煤的破碎、磨耗及分层 macroscopic kinetics based on the nucleation and growth of 会导致燃料反应器内气体的不完全转化。在反应器方面，建 solid product from molecular level. A model of inte