毒死蜱微胶囊化和释放性能表征.pdfVIP

中国农业科学 2007,40(12):2753-2758 Scientia Agricultura Sinica 毒死蜱微胶囊化及释放性能表征 赵 德，韩志任，杜有辰，慕 卫，刘 峰 （山东农业大学植物保护学院/ 山东省农药毒理与应用技术重点实验室，泰安 271018 ） 摘要：【目的】获得脲醛树脂制备毒死蜱微胶囊的配方，表征其释放性能，为优化该农药的使用性能提供依 据。【方法】利用生物摄像显微镜和激光粒度分布仪研究了成囊促进剂、分散剂和添加氯化钠对微胶囊制备的影响， 用气相色谱法表征毒死蜱微胶囊的释放动力学。【结果】配方中成囊促进剂选择 SMA，质量分数为 2.5％，分散剂 为PAAS，质量分数为2.0％，添加氯化钠，质量分数为0.4％，制备的微胶囊表面形貌良好，平均粒径约10 µm。 气相色谱法测定微胶囊的缓释性能，前5 d为初期快速释放阶段，符合一级动力学方程（ 2 R ＝0.9820），累计释放 量达到37.32％；5～42 d为匀速释放阶段，符合零级释放特征（ 2 R ＝0.9927）。【结论】以该配方得到的毒死蜱脲 醛树脂微胶囊具有良好的缓释性能，有助于延长控制期。 关键词：原位聚合；脲醛树脂；毒死蜱；微胶囊；释放性能 Preparation of Chlorpyrifos Microcapsules and Its Controlled Release Characteristics ZHAO De, HAN Zhi-ren, Du You-chen, MU Wei, LIU Feng (College of Plant Protection, Shandong Agricultural University, Shandong Key Laboratory of Pesticide Toxicology and Application Technique, Tai’an 271018) Abstract: 【Objective 】The controlled-release formulation of chlorpyrifos microcapsule encapsulated with UF-resin, and its controlled-release kinetics were studied for optimizing the bioefficacy of chlorpyrifos. 【Method 】The effects of encapsulating adjuvant, dispersant, and sodium chloride on encapsulation of microcapsule were investigated by biology photography microscope and photon correlation spectroscopy (PCS). The controlled-release characteristics were studied by gas chromatography. 【Result 】In the optimal formulation, the mass weights of Styrene Maleic Anhydride (SMA) as encapsulating adjuvant and Sodium Polyacrylate (PAAS) as dispersant were 2.5% and 2.0%, respectively. And adding sodium chloride with mass weight of 0.4% co