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Effects of Pretreatment Conditions on Redox Property over AuCo3O4CeO2 Material.pdf
JOuRNALOFCHINA 0RDNANCE
EffectsofPretreatmentConddJittlioonassoonn RRed—ox
PropertyoverAu/Co3O4/CeO2Material
SHAOJian—jun(邵建军),一,MAXiao—lei(马晓蕾),ZHUXi(朱锡)。
(1.PostdoctoralScientificResearchStationin92493Unit,PLA;2.91439Unit,PLA;
3.DepartmentofNavalArchitectureandOceanEngineering,NavalUniversityofEngineering,Dalian116041Liaoning,China)
Abstract:Au/Co304/CeO2materialsarepreparedusingconventionaldeposition—precipitationmethod.Theeffectsofcalci—
nationtemperaturesandpretreatmentconditionsonthecatalyticperformanceofAu/Co304/CeO2forCOlow-temperature
oxidation inhumidcircumstanceareinvestigated.Thesamplecalcinesat443K inflowingairexhibitedgoodactivityand
stabilityforCOoxidation.80%COconversionratecanbeachievedafter3000minwithafeedgascontained3.1%(妒w)
ofwatervapor.ThephysicalandchemicalpropertiesoftheAu/Co304/CeO2samplesarecharacterizedbyX—raydiffrac—
tion(XRD),temperature—programmedreduction (H2一TPR),andtransmissionelectronmicroscopy(TEM)techniques.
Thecharacterizedresultsshow thatthepreparedmaterialcalcined at443K hasaweak diffractionpeakofgoldspecies
observedbyXRD,thegraindiameterof3nm byTEM andbestredoxpropertyandthehighestactivityforCO oxidation
byH2一TPR atpropecalcinedtemperature.
KeyWords:physicalchemistry;Au/C%04/Ce02;redoxproperty;calcinationtemperatures;pretreatment
CLCNumber:0643.3 DocumentCode:A ArticleID:1673—002X(20O9)03—0203—06
CO oxidation.Based on the considerations。Au/
Introduction
Co304/CeO2mixedoxidespreparedby deposition—
I、hecatalyticoxidation ofCO atambienttem— precipitation method wereinvestigated forCO corn—
peratureshasextensiveusesin environmentalpollu— pleteoxidationinthepresentwork.Effectsofcalci—
tioncontrol,tailgascontr
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