壳聚糖磁性微球对偶氮品红的吸附.pdfVIP

第 3O卷第4期 中南民族大学学报 (自然科学版) V01．30No．4 2011年 12月 JournalofSouth—CentralUniversityforNationalities(Nat．Sci．Edition) Dec．2011 !--· 冗聚糖磁性微球对偶氮品红的吸附 察冬梅，刘明军，孙小梅，马 璐，张 威 (中南民族大学 化学与材料科学学院，分析化学国家民委重点实验室，武汉430074) 摘 要 利用反相悬浮交联法，以Fe。O 为核，制备了壳聚糖磁性微球．将其用于水中偶氮品红的吸附，研究了溶 液酸度、吸附时间、偶氮品红初始浓度、温度、离子强度对吸附的影响．结果表明：在40％，pH4．0，无盐条件下吸附 效果最佳 ，壳聚糖磁性微球对偶氮品红的饱和吸附量达到357．1mg／g．运用相关数学模型拟合实验数据得出，该吸 附同时符合Freundlich和Langmuir模型 (均R 0．96)．经3次重复使用再生后壳聚糖磁性微球对偶氮品红的吸 附率仍高于90％．该种新型吸附剂吸附能力强、速度快且易分离和可再生． 关键词 偶氮品红 ；壳聚糖；磁性微球；吸附 中图分类号 0629．9；0647．72 文献标识码 A 文章编号 1672-4321(2011)04-0036-05 AdsorptionBehaviorofM agneticChitosanM icrospheresforAzo-Fuchsin ChaDongmei，LiuMingjun，SunXiaomei，MaLu，ZhangWei (KeyLaboratoryforAnalyticalChemistryoftheStateEthnicAffairsCommission，CollegeofChemistryand MaterialsScience，South—CentralUniversityforNationalities，Wuhan430074，China) Abstract Magneticchitosanmicrosphereswerepreparedthroughinversesuspensioncross—linkingusingFe3O4asnucleus andtheadsorptionbehavioroftheadsorbentofrazo—fuchsinwasstudied．Variousfactorsaffectingtheadsoprtionbehaviorof magneticchitosanmicrospheresofrazo·fuchsin such astemperature，pH ，initial concentration and ionicintensitywere investigated．Theresultsindicatethatazo—fuchsinCna bequicklyremovedfrom waterwithhigh efficiency．Theoptimal acidityofradsoprtionwaspH 4．0．Theoptimaltemperaturewas40℃ ．Undertheseconditions．themaximum adsoprtion capacityofthemang eticchitosna microspheresofrazo—fuchsinis357．1mg／g．Theisotherm adsoprtionequilibrium isotherm confo1TustoLangmuirmodelaswellasFreundlich model，withcorrelationcoefficientsgreaterthan0．96．Inaddition，it wasfoundthatwhentheadsorbentwasusedthreetimes．itsremovalpercentageofrazo—fuchsinstillreached90 ％ ．showing thati