生物医用Ti_Nb_Ta_Zr合金的微观结构和性能.pdfVIP

第 20 卷第 6 期 中国有色金属学报 2010 年 6 月 Vol.20 No.6 The Chinese Journal of Nonferrous Metals June 2010 文章编号：1004-0609(2010)06-1195-08 生物医用Ti-Nb-(Ta)-Zr 合金的微观结构与性能 马秀梅，孙 威，杨永建 (北京工业大学 固体微结构与性能研究所，北京 100124) 摘 要：采用显微硬度测试、X 射线衍射分析和透射电子显微镜观察等方法，研究不同热处理后生物医用 Ti-35Nb-5Ta-7Zr 合金和 Ti-35Nb-7Zr 合金的显微硬度变化及微观组织特征，揭示 Ta 元素的添加对合金微观结构、 时效析出序列及性能的影响。结果表明：Ti-35Nb-5Ta-7Zr 合金比 Ti-35Nb-7Zr 合金具有更明显的时效强化效果； 固溶处理(ST) 后经 300 和 600 ℃时效处理，Ti-35Nb-5Ta-7Zr 合金的时效析出顺序可以描述为 β+α″(ST) 300 β+α 600 β+α+等温 ω，而 Ti-35Nb-7Zr 合金的时效析出顺序为 β+α″+淬火 ω(ST) 300 β+α+等温 ⎯⎯⎯→ ⎯⎯⎯→ ⎯⎯⎯→ 600 ω⎯⎯⎯→β+α；Ta 元素的添加抑制固溶处理过程中淬火 ω相的析出，提高时效过程中等温 ω相的析出温度。 关键词：生物医用材料；医用钛合金；Ti-35Nb-5Ta-7Zr 合金；Ti-35Nb-7Zr 合金；时效；微观结构；显微硬度 中图法分类号：TG 146 Microstructures and properties of biomedical Ti-Nb-(Ta)-Zr alloys MA Xiu-mei, SUN Wei, YANG Yong-jian (Institute of Microstructure and Property of Advanced Materials, Beijing University of Technology, Beijing 100124, China) Abstract: The variations of microhardness and microstructures for the biomedical Ti-35Nb-5Ta-7Zr and Ti-35Nb-7Zr alloys subjected to different heat treatments were studied by microhardness test, X-ray diffractometry and transmission electron microscopy. The effects of alloying element Ta on these variations and aging precipitation sequences were revealed. The results show that the aging strengthening effect in the Ti-35Nb-5Ta-7Zr alloy is more prominent than that in the Ti-35Nb-7Zr alloy. For the solution-treated Ti-35Nb-5Ta-7Zr and