嫁接法制备有机无机杂化催化剂研究进展精要.docVIP

嫁接法在有机无机杂化材料催化剂研究进展 摘 要 随着科学的发展，单一性质的材料已经不能满足人们的正常生活需要，复合化是现代材料发展的趋势，通过多种材料功能的复合，实现能互补和优化，可望制备性能优异的材料。催化剂通过共价键负载到固体材料上制备催化剂，一方面可以保持均相催化剂的高活性，另一方面载体为催化剂回收提供了有效的途径及合成方法，弥补了催化剂催化活性偏低和催化剂不能重复使用的缺点，具有十分重要的意义。 有机无机杂化材料在催化领域具有重大作用。催化剂通过各种途径负载到杂化材料上，形成负载型催化剂 。 本文主要介绍主要阐述嫁接法在有机无机杂化材料催化剂的应用，及其在精细化工和绿色化工上的左右。阐述的内容： 有机-无机杂化材料在环氧化物的研究应用。主要描述的是，均相金属配合物催化剂的固载化方法，重点讲述了嫁接法在环氧化的应用。 介孔材料为载体在多酸的研究应用。主要描述了，介孔材料在多酸催化中的应用及合成原理，举HMS小球负载钨磷酸例字简单说明了催化效果。 有机无机杂化材料在烯烃不对称环氧化催化剂应用。不对称催化是精细化工中有着重大意义和作用。这里面主要阐述了Mn（Salen）系列负载到有机无机杂化介孔材料的嫁接法的作用。 关键词　有机无机杂化材料；手型催化剂；嫁接 The progress of the grafted catalyst for organic-inorganic hybrid materials Abstract With the development of science, the single nature of the material can not meet peoples normal life needs, the composite is the development trend of modern materials, can complement each other and optimize a variety of composite materials function is expected to prepare performance material. Catalysts through covalent bond the load to the preparation of the catalyst in the solid material, on the one hand, can maintain a high activity of homogeneous catalysts, on the other carrier for the catalyst recycling provides an effective way and synthetic methods to make up for the catalytic activity of the low and the catalyst can not the disadvantage of re-use, has great significance. Organic-inorganic hybrid materials play a major role in catalysis. The catalyst load to the hybrid materials through various means, to form a supported catalyst.This paper describes mainly elaborated grafting catalyst in the organic-inorganic hybrid materials in fine chemicals and green chemical around. Elaborated: An organic - inorganic hybrid materials in the epoxide. Mainly described in Homogeneous Metal Complex Catalysts Immobilization methods, focus on the graft in the epoxidation. mesoporous material as a carrier in a multi-acid research applications. Mainly describes the mesoporous materials in acid catalysis and synthetic principle, give the HMS ball load PWA cases the wor