含酚废水处理毕业论文技术报告.docVIP

摘 要 苯酚是一种毒性很强的有机化合物，存在于许多工业废水中，严重危害着人类和动植物的健康。因此，除去废水中的苯酚是十分必要的。 目前，工业含酚废水的处理方法主要有吸附、萃取、离子交换、化学氧化法、光催化氧化法、活性污泥法和生物膜技术。本文采用酚醛反应法对高浓度含酚废水进行预处理，然后通过树脂的动态吸附对已经经过预处理的含酚废水进行苯酚含量的进一步降低。得到的结果如下： ⑴研究了深度缩合法对含酚废水的预处理效果。通过改变除酚效果的影响因素，即甲醛用量、硫酸用量、反应温度和反应时间，探索了这些影响因素对除酚效果的影响趋势。其他三个因素不变，改变其中一个因素，经实验得：废水中苯酚含量随甲醛用量的增加而减少，随硫酸用量的增加而减少，随反应温度的升高而减少，随反应时间的延长而减少。 ⑵从减少甲醛含量、延长反应时间方面做了几组实验，根据实验数据综合考虑，最终确定200ml废水加入10ml甲醛、1.5ml盐酸，在90℃下反应7小时，对含酚废水的预处理效果最佳。 ⑶研究了树脂吸附法去除废水中低浓度苯酚的效果。H-103树脂的动态吸附实验表明，500ppm的含酚废水以60ml/h的流速流过H-103树脂，经过10小时的动态吸附，树脂的吸附能力达到饱和，含酚废水达到排放标准。 关键词：含酚废水；除酚；酚醛反应；树脂动态吸附；H-103树脂 Abstract Phenol is a highly toxic of organic compounds, which exists in many industrial wastewater. It`s seriously harm to the health of human beings and animals and plants. Therefore, the removal of phenol in wastewater is necessary. At present,the main methods that industrial phenolic wastewater treatment contains adsorption, extraction, ion exchange process, chemical oxidation process, photocatalytic oxidation process, active sludge process and biomembrane technology. This study adopts phenolic reaction method to pretreat high-concentrated phenol wastewater, then through the dynamic adsorption resin to further reduce the phenol content of phenolic wastewater that have been pretreated. Main results were as follows: ⑴This study researched the effect the phenol wastewater pretreatment by phenolic reaction. By changing the factors—the amount of formaldehyde and sulfuric acid, reaction temperaturea and reaction time to explore the influence of these factors on the trend of removal of phenol. Concentration of phenol wastewater decreased with the increase of amount of formaldehyde and sulfuric acid, with the increase of reaction temperature and with extending reaction time. ⑵We made a few experiments from reducing formaldehyde, extending reaction time. According to the experimental data, the best effect of phenol wastewater pretreatment is under the following condition, that is adding 10ml formaldehyde and 1