Equilibrium relationships and equilibrium stage operation课件.pptVIP

2. Equilibrium of Gas and Liquid and equilibrium stage * * * Chapter 7 Equilibrium relationships and equilibrium stage operation * 1. Phase Rule F = C – Φ + 2 F = number of degrees of freedom, or variance C= number of components Φ= number of phases 2 —— only temperature and pressure may affect the equilibrium state. e.g.: In systems of two components, C=2；Φ=2； therefore, F = 2 - 2 + 2 = 2 * For binary distillation, F=2, there are four variables of interests: pressure, temperature, and the mole fractions of component A in liquid and vapor phases. If the pressure is fi