绿色化学2014_1.ppt

New greener way Silver catalyst is used to convert ethylene directly to the target molecule by using oxygen as the oxidant, which gives 100% atom utilization. The preparation of epoxypropane Traditional way New greener way Direct oxidation catalyzed by titania-silica To address the atom economy, the by-product D would vanish if the desired product is C. 3.4 原子经济反应的设计 The synthesis of α,β-unsaturated carbonyl compounds frequently involves the use of olefination protocols including but not limited to Wittig, Horner-Emmons-Wadsworth, Julia-Kocienski, etc., protocols. All of these suffer from l