水热合成ZnO及其光催化性质研究解析.docVIP

毕业论文 题 目 水热合成ZnO及其光催化性质研究 学 院 专 业 班 级 学 生 学 号 指导教师 二〇一五年月日 摘 要 本文采用水热法合成氧化锌，将氯化锌溶解后搅拌，加入表面活性剂后再搅拌，最后加入氢氧化钠置于反应釜中在170-200下反应，反应完毕后冷却至室温，将产物用蒸馏水离心清洗6次后至于鼓风干燥箱在80下干燥后得产物。实验主要研究反应温度、反应时间、溶剂种类、表面活性剂种类、表面活性剂的加入量、氯化锌的用量等变量对氧化锌形貌的影响，并对制备的氧化锌进行XRD表征。将生产的氧化锌在高温条件下掺氮，用甲基橙和亚甲基蓝对氧化锌进行光催化测试，用氙灯光源模拟太阳光照后，其在365 nm左右的紫外谱图吸收峰下降明显，说明氧化锌样品在特定波长的光线照射下具有一定的光催化效果结果。相比较而言，氧化锌对亚甲基蓝的光催化效果比对甲基橙的光催化效果好，掺氮后的氧化锌比未掺氮的对亚甲基蓝的光催化效果更为明显。 关键词：水热法；纳米氧化锌；掺氮；光催化 ABSTRACTIn this paper，the synthesis of zinc oxide hydrothermal method. After the dissolution of zinc chloride with stirring， adding a surfactant and then stirring， and finally placed in a reaction vessel was added sodium hydroxide to react at 170-200 . After cooling to room temperature， the product was washed six times with distilled water by centrifugation after completion of the reaction as for blast oven dried to give the product in 80 . We studied the influence of reaction temperature， reaction time， kind of solvent， surfactant type， the amount of surfactant is added， the amount of zinc chloride， zinc oxide and other variables on morphology， and zinc oxide were prepared by XRD analysis. The nitrogen-doped zinc oxide produced at high temperatures with methyl orange and methylene blue on zinc oxide photocatalytic test. After a xenon light source simulated solar illumination in the UV absorption spectrum around 365 nm decreased significantly， indicating zinc oxide sample has a photocatalytic effect results when exposed to light of a specific wavelength. In contrast， methylene blue zinc oxide photocatalytic effect of the photocatalytic effect of methyl orange than good， nitrogen-doped zinc oxide not doped with nitrogen ratio after the methylene blue photocatalytic effect is more obvious. Key words：Hydrothermal； Zinc Oxide； Nitrogen-doped； Photocatalytic 目 录 摘 要 I A