阿维菌素在土壤中的残留研究要点.doc

5%阿维菌素微乳剂在土壤中的残留研究 摘要 在农业生产过程中，化学农药的应用对提高农作物产量和促进生产力的发展起到了积极作用，。作为一种新型，它，对其在土壤中的残留分析研究对农业的发展有着重要的意义。 本课题建立了高效液相色谱法测定土壤中的残留量的分析方法。以乙酸乙酯为提取，经，高效液相色谱(检测器)测定。95.27%、95.47%、96.34 %，相对标准偏差分别为3.47%、2.29%、3.38%。由在土壤中的消解动态和最终残留结果表明，最终残留量小于mg/kg。 ；土壤；残留分析；液相色谱 esidues of 5% Avermectin micro-emulsion in the soil Abstract In the process of agricultural production, the application of chemical pesticides to improve crop yields and promote the development of productivity has played a positive role, but at the same time brings environmental pollution. Safety, low toxicity, high efficiency, no residue, no pollution of biological pesticide, get the favour of people, as a kind of new type biological pesticide abamectin, it has high efficiency, broad spectrum, long hold effect, easy degradation, the residues in the soil of analysis and study is of great significance to the development of agriculture. This subject set up a high performance liquid chromatography (HPLC) method was developed for the determination of abamectin in soil residue analysis method. With ethyl acetate as the extraction agent, after derivatization high performance liquid chromatography (HPLC) determination (FLD) detector. Abamectin in three different dosager,the average recovery are 95.27%, 95.47% and 96.34% , the relative standard deviation are 3.47%, 2.29% and 3.38% . Abamectin by digestion dynamics and final residues in the soil of results show that the half-life of abamectin was 5.2 days, abamectin final residues are smaller than the maximum residue limits of 0.02 mg/kg. Keywords: avermectin; soil; residue analysis; liquid chromatography  第一章 文献综述 化学农药残留引起的环境污染、人畜中毒问题已日益受到世人的普遍关注。随着人们健康意识的增强和环保意识的增强,安全、低毒、高效、无残留、无污染的生物农药,近年来正在蓬勃兴起。生物农药是用生物活体(菌丝体、伴孢晶体、昆虫病毒等)对特定的害虫具有控制特效而对公众具有安全性的天然农药。生物农药与化学农药相比,生物农药具有以下优点:无残留、无公害、不污染环境、特性强(即专一性作用于标靶有害生物)等。[1] 5%阿维菌素微乳剂是一种水性化生物农药，具有高效、广谱、持效期长、易降解等优点，通过对其在环境介质中的农药残留的分析检测，对环境保护、人类健康和农业的发展都有着重要的意义。 1.1阿维菌素的结构和性质 1.1.1化学结构 1979年，美国、日本科