Ca0.3(Li12Sm12)0.7TiO3微波介质陶瓷低温烧结地地研究.docVIP

文章编号：100-324X(2008)0？-0???-0? Ca0.3(Li1/2Sm1/2)0.7TiO3微波介质陶瓷的低温烧结研究 李月明1，宋婷婷1，尤 源2，胡元云2，刘维良1，唐春宝1 （1.景德镇陶瓷学院，江西 景德镇，333001；2.浙江正原电气股份有限公司，浙江 嘉兴，314003） 摘 要：采用传统陶瓷制备工艺，制备了掺杂Na2O–CaO–B2O3（NCB）氧化物Ca0.3(Li1/2Sm1/2)0.7TiO3（CLST）陶瓷，研究了NCB掺杂量与晶相组成、显微结构、烧结性能及微波介电性能的关系。结果表明NCB掺杂量在1～15wt%范围内没有杂相生成，晶相仍呈斜方钙钛矿结构。随着NCB添加量的增，陶瓷致密化温度和饱和体积密度降低，介电常数εr、无载品质因数与谐振频率乘积Qf值也呈下降趋势，频率温度系数τf向正方向增大。NCB能有效CLST陶瓷的烧结温度由1300℃降低至900 ℃。添加15 wt% NCB的CLST陶瓷在900 ℃烧结5 h良好的微波介电性能：εr ＝ ，Qf ＝ 1 GHz，τf ＝ 1 ppm/℃，满足高介多层微波器件的设计要求。 关键词：Ca0.3(Li1/2Sm1/2)0.7TiO3；Na2O–CaO–B2O3；低温烧结；微波介中图分类号：TM227 文献标识码：A Low-temperature Sintering of Ca0.3(Li1/2Sm1/2)0.7TiO3 Microwave Dielectric Ceramics Li Yue-ming1, Song Ting-ting1, You Yuan2, Hu Yuan-yun2, Liu Wei-liang1, Tang Chun-bao1 (1. Jingdezhen Ceramic Institute, Jingdezhen, 333001, China; 2. Zhejiang Zhenyuan Electric Co. Ltd., Jiaxing, 314003, China) Abstract: The NCB(Na2O–CaO–B2O3)-doped Ca0.3(Li1/2Sm1/2)0.7TiO3(CLST) ceramics were fabricated via the traditional ceramic process. The relation between NCB dopant contents and the crystal structure, microstructure, sintering behavior, and dielectric properties of CLST ceramics were investigated systematically. The results indicate that the second phases are not found within1 ~ 15 wt % range of NCB dopant contents and the major phase of CLST ceramics is still orthorhombic perovskite. With the increase of NCB content, the densification temperature and bulk density of CLST ceramics decrease, the dielectric constant εr and the product of quality factor and resonance frequency Qf value also decrease, and the temperature coefficient of resonant frequency τf increases to positive. NCB can effectively decrease the sintering temperature of CLST from 1300 ℃ to 900 ℃. The sample of CLST with 12.5 wt% NCB sintered at 900 ℃ for 5 h still has excellent dielectric properties: εr ＝ ，Qf ＝ 1 GHz，τf ＝ 1ppm/℃. The design demand of high dielectric constant and multilayer microwave components are satisfied. Keyword: Ca0.3(Li1/2S