WeatheringresistanceofwaterbasedUV-curedpolyurethane-acrylatecoatings分析报告.pdf

Polymer Degradation and Stability 83 (2004) 309–320 /locate/polydegstab Weathering resistance of waterbased UV-cured polyurethane-acrylate coatings a, a b C. Decker *, F. Masson , R. Schwalm a ´ ´ ´ ´ ´ Departement de Photochimie Ge nerale (UMR-CNRS No. 7525), Ecole Nationale Superieure de Chimie de Mulhouse, Universite de Haute-Alsace, 3, rue Werner, 68200 Mulhouse, France bPolymer Research Laboratory, BASF-AG, 67056 Ludwigshafen, Germany Received 9 June 2003; accepted 6 July 2003 Abstract The light stability of waterbased UV-cured polyurethane-acrylate (PUA) coatings has been tested in an accelerated QUV-A weatherometer. Infrared spectroscopy was used to monitor both the ultrafast polymerization of the acrylate double bond upon intense illumination, and the chemical changes occurring upon photoageing of 30 mm thick clearcoats. The UV-curing reaction was hardly affected by the addition of the HALS radical scavengers and UV absorbers needed to improve the light stability of water- based UV-cured PUA coatings. The a-hydroxyphenyl ketone used as photoinitiator was shown to disappear rapidly upon UV- curing and early QUV exposure, thus having no detrimental effect on the weathering resistance. The urethane linkage (C-NH) is the most sensitive to photodegradati