热孔计法表征水泥基材料孔结构的热力学计算模型.pdfVIP

· 194 · 硅 酸 盐 学 报 2012 年 第40 卷第2 期 硅 酸 盐 学 报 Vol. 40 ，No. 2 2 0 1 2 年 2 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY February ，2012 热孔计法表征水泥基材料孔结构的热力学计算模型 蒋正武，张 楠，杨正宏 ( 同济大学，先进土木工程材料教育部重点实验室，上海 200092) 摘 要：提出了一种采用热孔计法表征水泥基材料的内部微孔结构及其分布的新方法。利用热力学、相变等基本理论，建立了热孔计法表征水泥基材 料孔结构的热力学计算模型，并研究了该方法表征水泥基材料的各种孔结构特征参数。结果表明，所建立的热孔计法孔结构热力学计算模型可用于表 征水泥基材料中微孔的孔型、孔隙率、孔径分布等的孔结构信息，其结果具有再现性。 关键词：热孔计法；孔结构；水泥基材料；热力学；计算模型 中图分类号：TU528.2 文献标志码：A 文章编号：0454–5648(2011)02–0194–06 网络出版时间：2012–1–6 14:27:44 DOI ：CNKI:11-2310/TQ1427.003 网络出版地址：/kcms/detail/11.2310.TQ1427.003.html Thermodynamic Calculational Model for Pore Structure Characterization of Cement-Based Material by Thermoporometry JIANG Zhengwu ，ZHANG Nan ，YANG Zhenghong (Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 200092, China) Abstract: A method of thermoporometry (TPM) characterizing pore structure and pore distribution of cement-based material was proposed. The thermodynamic calculational model of pore structure characterization of cement-based material by TPM was estab- lished based on theormodynamics and phase change theories. The pore structure parameters of cement-based material were investi- gated by the TPM. The results indicate that the micropore information of cement-based materials such as pore shape, porosity and pore distribution can be characterized by the thermodynamic calculational model. Key words: thermoporometry; pore structure; cement-base material; thermodynamics; calculational model 混凝土结构的各种劣化过程如冻融[1] [2–3] 基材料。其中：氮吸附(nitrogen adsorption/desorp-