Ca-Al催化剂上甘油与碳酸二甲酯酯交换合成碳酸甘油酯.pdfVIP

Chinese Journal of Catalysis 36 (2015) 1759–1765 催化学报 2015年 第36卷 第10期 | a v a i l a b l e a t w w w. s c i e n c e d i r e c t . c o m j o u r n a l h o m e p a g e : w w w. e l s e v i e r. c o m / l o c a t e / c h n j c Article Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite a a b a, Liping Zheng , Shuixin Xia , Xiuyang Lu , Zhaoyin Hou * a Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang, China b Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China A R T I C L E I N F O A B S T R A C T Article history: A series of Ca-Al hydrocalumite with different Ca/Al ratios (1–6) were synthesized and used in the Received 23 March 2015 transesterification of glycerol with dimethyl carbonate (DMC) to glycerol carbonate (GC) under mild Accepted 16 May 2015 conditions. The calcined Ca-Al hydrocalumites were active with a selectivity toward GC that reached Published 20 October 2015 97% at 93% conversio