FabricationandCharacterizationofTailoredTiO2andWO3MWCNTCompositesforMethyleneBlueDecomposition.pdfVIP

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FabricationandCharacterizationofTailoredTiO2andWO3MWCNTCompositesforMethyleneBlueDecomposition.pdf

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FabricationandCharacterizationofTailoredTiO2andWO3MWCNTCompositesforMethyleneBlueDecomposition.pdf

2011 Chinese Journal of Catalysis Vol. 32 No. 6 Article ID: 0253-9837(2011)06-0926-07 DOI: 10.1016/S1872-2067(10)60208-2 Article: 926–932 Fabrication and Characterization of Tailored TiO2 and WO3/MWCNT Composites for Methylene Blue Decomposition * ZHU Lei, MENG Zeda, OH Won-Chun Department of Advanced Materials Science Engineering, Hanseo University, Chungnam 356-706, Korea Abstract: A sol-gel method was used to prepare WO /MWCNT-TiO composites. Their photocatalytic activities were evaluated by the deg- 3 2 radation of methylene blue (MB) solution under UV light. The catalysts were characterized by X-ray diffraction, specific surface area meas- urement, energy-dispersive X-ray analysis, transmission and scanning electron microscopy. Aqueous MB solutions of 100 ml were photode- graded by a small amount of the WO3/MWCNT-TiO2 composite under UV light irradiation. The photocatalytic data showed that the WO /MWCNT-TiO composite achieved a high rate of MB photodegradation. This was attributed to the use of MWCNT which can absorb 3 2 UV light to create photo-induced electrons, strong adsorption of dye molecules on the photocatalyst, and reduced recombination rate of elec- tron-holes in the WO /MWCNT-TiO composite due to the introduction of the WO semiconductor. 3 2 3 Key words: tungsten trioxide; titanium dioxide; multi-walled carbon nanotube; ph