干法腈纶聚合物性能控制分析与优化大学生大学生毕业设计论文.docVIP

干法腈纶聚合物性能 控制分析与优化 题 目：干法腈纶聚合物性能控制分析与优化 作 者： 陈 彬 指导教师： 王 芸 副教授 专 业： 化学工程与工艺 班 级： 化学工程与工艺专升本015（抚顺） 学 号： 0821503704 时 间： 二〇一〇年五月五日 摘 要 腈纶工业伴随经济高速稳定增长，社会需求量稳步增加，其发展前景可观，尤其是干法腈纶性能与用途优于湿法腈纶。随着科学技术和社会经济发展，市场对腈纶产品质量要求越来越高，如何发挥干法腈纶优势，增加市场份额，提升用户的信任度，是国内干法腈纶生产厂急需解决的问题。本文通过对聚合釜工艺条件的优化，以达到提高聚合物产品质量。 本文通过两个途径的实施：一、聚丙烯腈质量主要取决于三单体配比、系统中硫的分布、反应温度和pH值等要素的合理最优控制，对其理论分析，结合生产实际，给出聚合釜最佳工艺控制点。二、通过对聚合釜内液——固相流动状态分析，控制搅拌转速，改变聚合釜内进料方向，优化工艺。反应数据过程跟踪，工业试验结果表明：反应转化率得到提高，分子量分布宽度变窄，产品疵点降低，优级品率得到大幅度提高，实现优化聚合物性能的目的。 关键词：聚合釜 聚丙烯腈 温度 转化率 分子量 The dry acrylon polymer performance optimization. Abstract Along with the rapid development of the economic, the social demand of acrylic products is increasing. The development prosped of the acrylic fiber industry is optimistic, especially the dry acrylon method. At the same time, the market needs higher quality acrylic products. The domestic dry acrylon company should urgently resolve these problems: how to exert the advantage of the dry acrylon, increase its market share and promote the trust degree of customers. This paper studies on the optimization of the technic conditions of the polymerizer in order to improve the quality of polymer. In this paper, mainly research from two way: First, the quality of polyacrylonitrile mainly is decided by the distribution of the sucfur and the three monomers, the reaction temperature and the pH value. I try to find the best condition through studying theoretical analysis and producing. Second, through studying on the flow state analysis of the liquid phase and the solid phase in polymerizer, the stirving rate, the feeding direction, the technology process and tracking the reaction data, the experiment result shows: the conversion rate has been improved. The width of the molecular weight distribution become narrow. The product defects have been reduced. As a result,