丁苯橡胶无烟煤复合材料的制备应用 毕业论文.docVIP

摘 要 本课题以无烟煤为原材料，经酸浸处理后，以硅烷偶联剂、硬脂酸为表面改性剂，在行星式球磨机中进行研磨改性，将改性后的无烟煤填充到丁苯橡胶中制备无烟煤/橡胶复合材料。 采用比表面积、粒径、接触角及堆积密度等指标对无烟煤的酸浸和改性效果进行了表征，确定其最佳实验条件为：硫酸浓度为60%、水浴温度60℃、酸浸时间2小时；硅烷湿法改性，改性剂用量2.8%。对无烟煤/丁苯橡胶复合材料的力学性能进行了测试，并探讨了填料的用量、改性剂的类型等因素对复合材料力学性能的影响。结果表明：复合材料的力学性能得到了明显的改善。本研究为无烟煤在橡胶中的应用提供了有力的数据支持，改变了传统对煤炭资源应用的不合理性，避免环境的污染和资源的浪费，而且还能大幅度降低聚合物基复合材料的成本，是煤洁净高效利用的新途径。 关键词；力学性能 ABSTRACT The subject was studied by basing on the characteristics of the anthracite, taking sulphuric acid to purification , with silane coupling agent and stearic acid as surface modifier, using panetary ball mill to ultrafine the modified anthracite, the modified anthracite will be filled to the stuber, preparing anthracite / stuber composites. A series of research and analysis were conducted by anthracite surface area, particle size, contact angle and packing density of powder characteristics, the acid leaching and modified method the optimal conditions were 60% sulfuric acid, water bath temperature 60 ℃, acid leaching time 2 hours. Silane wet modification, modified dosage of 2.8%. And anthracite / stuber composite mechanical properties were characterized and tested, and discussed the amount of filler, different modifier factors on the mechanical properties of composite materials, the results show that the mechanical properties of composite materials has significantly improvement.The results of this study anthracite applications in stuber which offer strong in the data support,and it changed the traditional application of the irrationality of coal resources,avoiding environmental pollution and waste of resources, but it also significantly reduces the cost of polymer matrix composites, which it is a new way to use clean and efficient of coal. Keywords：anthracite；acid leaching；refining；surface modification；mechanical propertie 目 录 摘 要 I ABSTRACT II 1 绪论 1 1.1无烟煤的特性 1 1.1.1储量和地位 1 1.1.2国内外研究现状 5 1.2无烟煤的应用 6 1.2.1导电防静电类聚合物/煤复合材料 6 1.2.2绝缘类聚合物/煤复合材料 7 1.2.3阻燃类聚合物/煤复合材料 8 1.2.4新型功能性复合材料。 9 1.2.5无烟煤的工业用