朝天罐根化学成分的研究.pdfVIP

第 34 卷第 4 期 Vol.34 ，Issue 4 2009 年 2 月 February ，2009 Chemical constituents in roots of Osbeckia opipara 1,2,3 1 1,3 1,3 1,4* WANG Hongsheng ，WANG Yuehu ，SHI Yana ，LI Xingyu ，LONG Chunlin (1. Kunming Institute of Botany，Chinese Academy of Sciences，Kunming 650204 ，China; 2. Henan Institute of Science and Technology，Xinxiang 453003 ，China; 3. College of Landscape and Horticulture，Yunnan Agricultural University，Kunming 650201 ，China; 4. College of Life and Environmental Sciences，Central University for Nationalities，Beijing 100081 ，China） [Abstract] Objective：To study the chemical constituents of the roots of Osbeckia opipara. Method ：Repeated column chromatography over silica gel，RP-18 and Sephadex LH-20 ，and preparative thin layer chromatography （PTLC ）were used to isolate the compounds ，whose structures were determined by spectroscopic methods by direct comparing spectral data with those reported references. Result ：From the MeOH extract of the roots O. opipara，twelve compounds were isolated and identified as follows ： lasiodiplodin （1），de-O- methyllasiodiplodin （2 ），2 ，3- dihydro-2-hydroxy-2，4-dimethyl-5-trans-propenylfuran-3-one （3 ）， integracin （4 ），5α，8α-epidioxy- （22E ，24R ）-ergosta-6，22-dien-3β-ol （5 ），3，3 ，4 -tri-O-methylellagic acid （6 ），5-hydroxymethyl furaldehyde （7 ），vomif