通过植入聚丙烯亚胺碳纤维界面增强超临界甲醇详解.ppt

Improving the interfacial properties of carbon fiber reinforced epoxycomposites by grafting of branched polyethyleneimine on carbon fibersurface in supercritical methanol Carbon fibers (CFs) havebecome ideal reinforcements for polymer matrix composites. The mechanical properties of composites are influenced not only by the intrinsic chara-cteristics of CF and epoxy resin, but also by their inter-facial adhesion . The interfacial adhesion depends largely on molecular interfacial structure and interactions. However, the non-polar, highly stable and smooth graphitic surface of CF makes it difficult to provide desire interactions without CF surface modification. ?Introduction Functionalization of PEI onto CF ?Experimental Procedure ?Results and discussion 1.Surface chemical elemental and structure composion 2.Surface topography of CF 3.Dynamic contact angle analysis 4.Interfacial property testing 5.Impact property testing 6.Single fiber tension testing ?Conclusions Branched PEI was grafted onto the CF surface by chemical reaction in the conventional and supercritical methods. The experimental results suggest that the PEI could increase the polarity,wettability and CF surface roughness, and the supercritical methanol was also able to improve the grafting reaction efficiency between CF and PEI. The IFSS, ILSS and impact resistance of CF-g-PEI and CF-g-s-PEI increased significantly compared with the untreated CF, especially for CF-g-s-PEI. The reinforcing and toughening mechanisms were also explored. Functionalization of PEI in the supercritical methanol did not lead to any discernable decrease in single fiber tensile strength. CFs that are chemically grafted with PEI by supercritical methanol can be implemented easily and show great potential for use as novel reinforcements in high performance composites. Thank you for your listening!