四氟硼酸离子液体应用于锂离子电池的研究 毕业论文.doc

SHANDONGＵＮＩＶＥＲＳＩＴＹ　ＯＦ　ＴＥＣＨＮＯＬＯＧＹ 毕业论文 四氟硼酸离子液体应用于锂离子电池的研究 学 院： 化学工程学院 专 业： 化学工程与工艺 学生姓名： 学 号： 1011081081 指导教师： 2014年6月摘 要 离子液体作为绿色高效的溶剂，如今已成为合成化学研究的热点方向之一。本文在前人的基础上，合成了[Bmim]BF4，并将该离子液体作为锂离子电池电解液应用到锂电池的合成中。本文使用合成离子液体，并。最后将所得离子液体用作锂离子电池电解液，进行锂电池电化学窗口测试、电池的常温充放电循环性能测试等。 测试结果表明，中间体和四氟硼酸离子液体的红外光谱与标准的谱线图基本符合，所以得到的产物较纯；离子液体电导率的测试结果表明随着温度升高，电导率增大；锂电池电化学窗口测试是5.15V，说明锂电池较稳定；[Bmim]BF4与正极材料相容性较好，但两者略有差别 ，LFP较LCO相容性更优。在锂盐浓度为0.8mol·L-1时，与0.5mol·L-1以及1.0mol·L-1浓度的电解液相比，合成锂电池容量较高，且相容性更好。 关键词：四氟硼酸离子液体，性能测试Abstract Room temperature ionic liquids with its own advantages become one of the hot research direction of synthetic chemistry. We synthesized [Bmim]BF4 on the basis of previous . The ionic liquids used for the synthesis of lithium batteries as lithium-ion battery electrolytes. In this article, we use the microwave method to synthesize ionic liquids, and tested the performance of the intermediate and ionic liquid. Finally, we used it in lithium batteries and tested its performance. The results show that intermediates and tetrafluoroborate ionic liquids with standard IR spectral figure in line, therefore, the pure product was obtained. Test results showed that the conductivity of the ionic liquid as the temperature increases, the conductivity increases; Lithium electrochemical window test is 5.15V, explain more stable lithium for lithium-ion batteries; By the operating conditions, a stable discharge capacity of the battery reached only 50% of the theoretical value. However, after 10 cycles, the capacity is almost no attenuation. [Bmim]BF4 is good compatibility with the cathode material. LFP is slightly different from LCO, and LFP is better. In the lithium salt concentration of 0.8mol·L-1 , the lithium battery will be higher-capacity and better compatibility, comparing with 0.5mol·L-1and 1mol·L-1. Keywords: [Bmim]BF4, Cathode material, Lithium batteries, Performance testing目 录 摘要 I Abstract II 目录 III 第一章 绪论 - 1 - 1.1 离子液体简述