新型梳状聚烷基醚酯相变材料的制备 毕业论文.docVIP

天津工业大学 毕业梳状聚烷基醚酯相变材料的制备 姓 名 学 院 专 业 指导教师 职 称 2013年 5 月 20日 摘 要 本文采用醇钠-酰氯法的实验原理，以聚乙二醇烷基醚作为工作物质，与钠反应后，再与不同配比的（甲基）丙烯酰氯反应来制备相变材料。通过理论与实验相结合的研究方法逐步改善（甲基）丙烯酸单聚乙二醇烷基醚酯合成的条件以达到期望的状态，并对其进行聚合，同时进一步研究梳状相变材料的性能。通过本课题的研究，将合成出一种新型的梳状相变材料。这将对相变材料以后的应用起到一定的理论指导作用，并为高分子材料在其他领域的应用起到一定的推动作用。具体工作如下： 1、在聚乙二醇十六烷基醚与丙烯酰氯不同物质量比的条件下合成了丙烯酸单聚乙二醇十六烷基醚（n=2），通过产率曲线图确定最佳物质的量比，并对其进行聚合。通过FTIR、1HNMR及DSC等对产物的结构进行了表征和热性能的研究。 2、通过丙烯酸单聚乙二醇十六烷基醚（n=2）的合成的最佳物质的量的比，制备了甲基丙烯酸单聚乙二醇十六烷基醚酯、丙烯酸单聚乙二醇十八烷基醚酯和甲基丙烯酸单聚乙二醇十八烷基醚酯。并通过自由基聚合得到其聚合物。并对其进行聚合。通过FTIR、1HNMR及DSC等对产物的结构进行了表征和热性能的研究。 关键字：梳状相变材料；；高分子材料 ABSTRACT The principle of using alcohol sodium chloride method, with polyethylene glycol alkyl ether as the working substance, and sodium after reaction, with different ratio of (methyl) archly chloride is prepared by reaction of phase change material. Methods through the combination of theory and experiment of the gradual improvement of (methyl) conditions of acrylic acid polyethylene glycol alkyl ether ester synthesis to achieve the desired state, and carries on the polymerization performance at the same time, further research on the comb of phase change materials. Through the research, the synthesis of a novel comb phase change material. This will to a certain theoretical guidance for the application of phase change materials later on, and as to promote the application of polymer materials in other areas of the. The specific work is as follows: 1、in the condition of different mass ratio of the polyethylene glycol sixteen alkyl ether with archly chloride synthesis of acrylic acid polyethylene glycol sixteen alkyl ether (n=2), the yield curve to determine the optimal ratio of the amount of substance, and its polymerization. Through the FTIR, 1HNMR and DSC on the structures of the products were investigated to characterize the thermal performance and. 2、by acrylic acid polyethylene glycol sixteen alkyl ether (n=2) is the best mater