结晶提纯副产硫酸亚铁数学模型介绍.docVIP

结晶法提纯钛白副产硫酸亚铁的数学模型与实验研究 张克宇1,2,3，吴鉴1,2,3，赵泉峰1,2,3,，姚耀春1,2,3* 1）（昆明理工大学 真空冶金国家工程实验室，昆明 650093） 2）（昆明理工大学 云南省有色金属真空冶金重点实验室云南省复杂有色金属资源清洁利用国家重点实验室培育基地Mn、Mg、Zn、NiTQ125.14; TQ019; TQ026.5 文献标识码：A 文章编号： Numerical Model and Experimental Research for Purification of Titanium Dioxide Byproduct Ferrous Sulfate by Crystallization Zhang Keyu1,2,3, Wu Jian1,2,3, Zhao Quanfeng1,2,3, Yao Yaochun1,2,3 (The National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China) (Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China) （State Key Laboratory Breeding Base of Complex Nonferrous Metal Resources Clear Utilization in Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China) Abstract：In order to reclaim titanium dioxide byproduct ferrous sulfate, crystallization method was taken to purify the byproduct ferrous sulfate and find out the influence of times of crystallization and string speed on the purification process. The impurity segmentation and mass transfer were also analysed in crystallization process. A numerical more of crystal purity prediction used for the prediction of the impurity concentration after several times of crystallization was proposed on basis of the solid-liquid boundary layer theory of impurity diffusion. The experimental results indicate that the purification of byproduct ferrous sulfate by crystallization is feasible, and the analysis of the AAS show that the removal result of 4 impurity ions(Mn、Mg、Zn、Ni) are effective. The proposed numerical model of crystal purity prediction can used to predict the change of impurity concentration, especially the low concentration of impurity, with the times of crystallization. Because of the string in crystallization process, the impurity segmentation is influenced by the changing of the solid-liquid boundary lay between crystal and solution.（根据我