烷烃和环烷烃要点解读.ppt

写出乙烷一氯代反应机理的链引发与链增长的 步骤？ 试说明该反应不大可能生成CH3Cl的原因？ 问题2-1 后一反应链增长的第一步(限速)是吸热的，难于进行 When methane is chlorinated, traces of chloroethane are found among the products. How is it formed? Of what significance is its formation in reaction mechanism. 形成了甲基自由基中间体 问题2-2 Chlorination reactions of certain higher alkanes can be used for laboratory prepa- rations. Examples are the preparation of neopentyl chloride （新戊基氯）from neopentane and cyclopentyl chloride from cyclopentane. What structural feature of these molecules makes this possible? 问题2-3 练习题： 1. 沸点由高至低排序： 2. 自由基稳定性排序： (3)(1)(2) (3)(2)