紫外协同二氧化氯去除三氯生.docVIP

UV协同ClO2去除三氯生及其降解产物的研究 李玉瑛,2，何文龙1,2，李青松2,*，金伟伟2,3，陈国元2，李国新2 五邑大学化学与环境工程学院，广东，江门529000；2.厦门理工学院水资源环境研究所，福建，厦门361024；3.浙江工业大学建筑工程学院，浙江，杭州310014) 摘要：采用UV/ClO2工艺对三氯生(TCS)的去除进行了研究，考察了初始pH、ClO2投加量、TCS初始浓度、腐殖酸(HA)在UV/ClO2联用工艺中对TCS降解的影响。研究表明，UV/ClO2工艺可以有效去除TCS且具有协同作用，光强为6.5μW/cm2、ClO2投加量为0.5mg/L和TCS浓度为300μg/L时，单独UV和ClO2在1min内对TCS的去除分别为5%和84.93%，UV/ClO2联用工艺TCS在1min内去除可达到99.13%。试验范围内(pH=6~9)随着pH的增大TCS去除率从99.4%升到99.63%；增大ClO2投加量可以提高TCS的去除，ClO2投加量从0.5mg/L到1.5mg/L时TCS去除率由98.1%提高到99.89%；TCS初始浓度与去除率呈负相关，初始浓度从100μg/L到500μg/L时TCS去除率由98.1%下降到94.39%；低浓度的腐殖酸有利于TCS的去除，高浓度的腐殖酸则反之。GC/MS对TCS的UV、ClO2和UV/ClO2的降解产物分析表明TCS的主要降解产物包括2,4-二氯苯酚(2,4-DCP)、2,7-二氯代二苯并-对-二噁英(2,7-DCDD)等。 关键词：UV/ClO2；三氯生；去除；GC/MS；降解产物 中图分类号：TU991.2 文献标识码：A 文章编号： Study on removal of triclosan with the method of UV/ClO2 and its degradation products Li Yuying1,2,He Wenlong1,2,Li Qingsong2,*,Jin Weiwei2,3,Chen Guoyuan2,Li Guoxin2 College of Chemistry and Environmental Engineering,Wuyi University,Jiangmen 529000,Guangdong,China;2.Water Resources and Environmental Institute,Xiamen University of Technology,Xiamen 361024,Fujian,China;3.College of Civil Engineering and Architecture, Zhejiang University of Technology, Hangzhou 310014, China) Abstract:The UV/ClO2 process on triclosan(TCS) removal were studied,investigating the initial pH,dose of ClO2,initial concentration of TCS,humic acid(HA) on the UV/ClO2 combined process to the influence of degradation of TCS.Research shows that UV/ClO2 process can effectively remove TCS and has a synergistic effect,when light intensity was 6.5μW/cm2,dose of ClO2 was 0.5mg/L and the concentration of TCS was300μg/L, the separate of UV and ClO2 in 1min to the removal TCS reached only 5% and 84.93% respectively,while TCS removal may up to 99.13% in 1 min through the UV/ClO2 combined process. In test conditions (pH=6~9) with The increase of pH the removal rate increased from 99.4% to 99.63%;Increasing dose of ClO2 may promote TCS removal,the dose of ClO2 from 0.5mg/L to 1.5mg/