模拟印染废水CWAO法处理中浸渍型钌催化剂的教程.doc

模拟印染废水CWAO法处理中浸渍型钌催化剂的研究 廖伟明,钟展柔，郭晓云，耿旭，谢书坤,郑成林韩山师范学院 化学系 521041 摘要：采用催化湿式空气氧化法对甲基橙模拟印染废水进行处理，以等量浸渍方法制备Ru系列催化剂，以水样脱色率和催化剂在水样中溶出的金属离子浓度表征催化剂的活性与稳定性，并对催化剂进行XRD、SEM 、FT-IR表征。结果表明：活性组分配比为Ru:Cu:Fe:Ce:La= 1:0.5:0.5:0.5:0.5的催化剂，对甲基橙模拟印染废水的脱色率高达98.5%，反应后各金属组分的溶出浓度也较低，其活性和稳定性相对较高；1wt%Ru催化剂的活性组分主要以γ-Al2O3、RuO2、La2O3、La2(CuO4)和CeO2的形式存在，催化剂表面相对平整、呈薄片状，催化剂在1070 cm-1、1650 cm-1和3450 cm-1附近出现较强红外吸收峰。 关键词：甲基橙模拟印染废水催化湿式氧化浸渍型钌催化剂 Research on Impregnated Ruthenium Catalyst of Simulation Printing and Dyeing Wastewater Treatment with CWAO Method Department of Chemistry, Hanshan Normal University, Chaozhou 521041, China Abstract: In the treatment of methyl orange analog dyeing wastewater by catalytic wet air oxidation method, the series of Ru catalysts was prepared with the equal amount impregnation method and the catalyst activity and stability were characterized by the decolorization rate of the water samples and the eluted metal ion concentration from the catalyst of the water samples. XRD, SEM, FT-IR were used to characterize the catalyst. The results show that: when active allocation ratio of the catalyst was Ru:Cu:Fe:Ce:La = 1:0.5:0.5:0.5:0.5, the degradation rate of methyl orange could reach up to 98.5% . And the concentration of each metal component eluted lower after the reaction, while its activity and stability were relatively high. The active component of 1wt % Ru catalyst mainly existed as the form of γ-Al2O3, RuO2, La2O3, La2(CuO4) and CeO2. The surface of catalyst was relatively flat and flaky. Catalyst appeared strong infrared absorption in the vicinity of 1 070 cm-1, 1 650 cm-1 and 3450 cm-1. Keuwords: methyl orange analog dyeing wastewater catalytic wet air oxidation activity and stability Ruthenium catalyst degradation rate;infrared absorption 1 引言 随着工业的迅猛发展，进入水体的化工合成物质数量和种类越来越多，印染废水即是其中危害极大的废水之一[1]。印染废水主要包括染料生产废水和印染工业废水，其组分复杂、色度高、COD和BOD浓度高、悬浮物多、水质及水量变化大、难降解，是较难处理的工业废水之一[2]。印染废水的处理方法主要包括生物氧化法、氧化法(化学氧化、光催化法、微波协同法)、吸附法、混凝法和电化学法等[3-4]。史玲等[5]在常温常压下采用湿式氧化法降解印染废水，使