09章_可逆电池的电动势及其应用课程.ppt

Dynamics electrochemistry Dynamics electrochemistry A Tafel plot is used to measure the exchange current density (given by the extrapolated intercept at ( = 0) and the transfer coefficient (from the slope). Dynamics electrochemistry In a simple model of the Nernst diffusion layer there is a linear variation in concentration between the bulk and the outer Helmholtz plane; the thickness of the layer depends strongly on the state of flow of the fluid. Dynamics electrochemistry Dynamics electrochemistry The change of potential with time and the resulting current/potential curve in a linear-sweep