基于胆酸、喹啉、羟基酰胺-二芳烯化合物的合成及性质研究.ppt

基于胆酸、喹啉、羟基酰胺-二芳烯化合物的合成及性质研究 一、基于胆酸—二芳烯化合物的合成及性质研究 二、基于PPQ—二芳烯化合物的合成及性质研究 三、基于羟基酰胺—二芳烯化合物的合成及性质研究 主要内容 一、基于胆酸-二芳基乙烯化合物 DT-1 DT-1 主要合成路线 DT-1o化合物的光化学性质 Figure 1. Absorption spectral changes of diarylethene 1 by photoirradiation (5.0 × 10-5 mol L-1) and PMMA film (10%, w/w). Figure 2. The changes in fluorescent emission spectra of diarylethene 1 by photoirradiation at room temperature: (A) in water (5.0 × 10-5 mol L-1), excited at 259 nm; (B) in a PMMA film (10%, w/w), excited at 317 nm. A B Figure 3. (A) Thermal fading of 1 in methanol / water binary solution (v/v = 1/19) (5.0 × 10?5 mol L-1) at various temperature. (B) Fatigue resistance of 1 in methanol / water binary solution (v/v = 1/19) (5.0 × 10?5 mol L-1) at room temperature. (A) (B) Figure 4. Photoconversion ratios of diarylethene 1 in methanol by HPLC analysis with 297nm light at different time: 0 min, 0.5 min, 1 min, 2 min, 3 min, 6 min, 15 min, 30min. DT-2 DT-5 DT-2o和5o化合物的光学性质 DT-2 DT-5 DT-2 DT-5 二、基于PPQ-二芳基乙烯化合物 UV/Vis absorption spectra changes Changes in the fluorescence of 1 induced by NaOH/HCl and light stimuli in methanol (5.0 × 10 ?5 mol L ?1 ): (A) fluorescence change, excited at 356 nm; (B) 1o induced by NaOH/HCl; (C) 1o′ induced by photoirradiation; (D) 1c induced by NaOH/HCl. Changes in the absorption and the fluorescence spectral of 1o by the addition of various metal ions in methanol (2.0 × 10–5 mol L–1). 三、基于羟基酰胺-二芳基乙烯化合物 谢 谢！ 欢迎各位老师提出宝贵意见！