电芬顿泥浆反应器中羟基自由基生成影响因素分析-农业环境科学学报.docVIP

电芬顿泥浆反应器中羟基自由基生成影响因素分析( 1,2，郭书海1*，1,2，1，李凤梅1 （1. 中国科学院沈阳应用生态研究所，沈阳 110016；2. 中国科学院大学，北京 100049）摘 要：采用高效液相色谱法，以水杨酸为羟基自由基（·OH）捕获剂，电芬顿泥浆反应器中影响·OH的生成量和检出准确度的关键因素。结果表明，向反应器内加入电解质（无水硫酸钠），5 g·L-1左右，可增加·OH生成量，且在较长时间段内使·OH瞬时浓度维持在较高水平；反应器内泥浆初始pH为3时，生成·OH的量大于初始pH为5和11时的生成量；装置中电极间距为5 cm时，生成·OH的量最高；加入适量水杨酸溶液，控制初始浓度在00 μmoI·L-1，可以较准确地间接表征瞬时·OH生成量。芘污染供试土壤的削减实验证明，加入适量的有机物可以减少·OH的自身淬灭。结果显示，电芬顿技术在适当的条件下可生成大量的·OH，从而快速有效地削减有机污染物。 关键词：电芬顿泥浆反应器；羟基自由基；影响因素；水杨酸；2,5-二羟基苯甲酸 Analysis of Influencing Factors?on Hydroxyl Radical Forming in the Electro—Fenton Slurry Reactor Abstract: Slurrying has been proven to be effective and efficient in pretreatment of soil organic contamination. Contaminated soil could be oxidized and remediated through integrating slurrying and Electro-Fenton treatment procedures.. This study was designed to investigate the key factors influencing ·OH generation and detection accuracy in Electro-Fenton based slurry bioreactor. and Salicylic acid was adopted as ·OH trapping reagent. Results indicated that generation rate of ·OH increased and maintained at a high level when electrolyte (anhydrous sodium sulfate) was maintained at the level of 5 g·L-1. Higher concentrations of ·OH was founded in the sample where initial pH value was set at 3 than in those samples where initial pH value of 5 and 11. Electrode spacing experiments demonstrated the highest amount of ·OH with the space set at 5 cm. Instantaneous generation rate of ·OH could be calculated accurately when the concentration of salicylic acid was kept at the level of 400 μmoI·L-1. Remediation experiments on pyrene-contaminated soil showed that the addition of certain amount of organic matter could reduce ·OH quenching. The study implied that Electro-Fenton could produce large amounts of ·OH under the proper controlled environment, and thereby degrade organic pollutants rapidly. Key words: Electro-Fenton slurry reactor; hydroxyl radical; influence factor; salicylic acid; 2,5-Dihydroxybenzoic acid 近年来，污染土壤修复越来越受到重视与关注