2008讲稿(第7章)胶体化学综述.pptVIP

Gibbs Equation：（推导过程见书） （7－8） Г2（1）－Surface excess of solute， index（1）present the Gibbs surface is located atГ1＝0. a2－activity of solute； γ－surface tension of the solution. For dilute solution，a may be substituted by c . （7－9） or （7－10） The concentration of solute in σ is higher than that in the solution. It is positive adsorption of the solute in the σ phase. For then c↑→γ↓，Г2（1）0， For then c↑→γ↑，Г2（1）0， The con