稀土离子掺杂钼酸钇钠单一相白色荧光粉的水热合成与发光性能教程.docVIP

编号 本科生毕业论文 稀土离子掺杂NaY(MoO4)2白色荧光粉的合成与性能 Hydrothermal Synthesis and Luminescence Properties of Rare-earth Ions Doped NaY(MoO4)2 Single-phase White Phosphor 化学 二〇一年六月 稀土离子掺杂NaY(MoO4)2白色荧光粉合成与性能 摘 要 稀土发光材料在固体照明，平板显示，激光器及生物标记领域有着广泛的应用。钼酸盐基质具有优良的物理和化学特性，尤其是稀土离子掺杂钼酸盐具有良好的发光特性和化学稳定性，可以作为白光发光二极管（LED）用的荧光粉本文采用水热法制备了Y(MoO4)2: Eu3+，NaY(MoO4)2: Tb3+和NaY(MoO4)2: Tb，Eu3+荧光粉，通过调节掺杂稀土离子的浓度比来实现色发光。利用X-射线衍射仪（XRD）和荧光光谱（PL）对样品的荧光性质进行了表征，研究稀土掺杂Y(MoO4)2材料的发光性质和能量传递过程。通过调节稀土离子的掺杂量，荧光粉的颜色可调控。 Y(MoO4)2 发光材料 能量传递 Abstract Rare earth luminescence materials are widely used in the fields of solid-state lighting, flat panel display, catalysis, laser devices and biological labeling. It is well known that molybdate have excellent physical and chemical stability. In particular, rare earth ions doped molybdate compounds exhibit wide luminescent properties, and they have been widely investigated in the phosphors for white light emitting diodes (LED). In this dissertation, NaY(MoO4)2: Eu3+, NaY(MoO4)2: Tb3+ and NaY(MoO4)2: Eu3+,Tb phosphors were prepared by hydrothermal method. The multicolor emissions have been achieved via adjusting the ratio of rare earth ions doping concentrations. The phase and fluorescence properties of the samples were characterized by X-ray diffraction (XRD) and fluorescence spectrometer (PL). The luminescence properties and energy transfer process of rare earth ions doped NaY(MoO4)2 materials were discussed also. By adjusting the doping amount of ions, the phosphor color can be regulated. Key words: Hydrothermal method; NaY(MoO4)2; Luminescence materials; Energy transfer 目 录摘 要 I Abstract II 目 录 III 第1章 绪 论 1 1.1 引 言 1 1.2 1 1.2.1 白光LED现状及发展趋势 1 1.2.2 白光LED实现方法 2 1.2.3 单一基质白光LED用荧光粉 3 1.3 钼酸盐发光材料 1.3.1 钼酸盐的结构 3 1.3.2 钼酸盐体系发光材料 4 1.4 稀土钼酸盐发光材料的制备方法 5 1.4.1 溶胶-凝胶法 6 1.4.2 燃烧合成法 6 1.4.3 溶剂热合成