无机-有机纳米复合的进展精编.ppt

Advance in Inorganic-Organic Nanocomposites Reporter： 余洋 Teammate： 赵雪宇 胡海波 钱凯 李亮亮 王海涛 钱益武 Outline With the great progress of our lives and development of technology, human race is demanding longer lives and more advanced medical methods. Nanometer materials is the most promising in the 21st century Organic–inorganic hybrid materials do not represent only a creative alternative to design new materials and compounds for academic research, but their improved or unusual features allow the development of innovative industrial applications. Ⅱ.Preparation methods Sol-gel In situ photopolymerization Intercalation Self-assembly Irradiation 1.Sol-gel preparation Fig10:Phase composition of the samples sintered at different temperatures 600 ?C, 700 ?C, 800 ?C and 900 ?C. Fig11:TEM micrograph of HA nanopowders sintered at 600 ℃. 2.In situ photopolymerization TEM images of as-prepared nanoparticles 3.Intercalation method X-ray powder diffraction Electrical conductivity measurements Conclusions The intercalated polymer chain favors the monolayer arrangement with the thiophene rings lying parallel with the host layers. which should be advantageous for transportation of electrons between the organic and inorganic components. the polymer/MoS2 nanocomposites can be modified, though the different guest–host charge transfers, by incorporating other conducting polymers and their doping, which make them applied in the electronic devices, such as LED, sensors and electrodematerials in Li-batteries. 纳米材料被誉为21世纪最有前途的材料, 其粒子尺寸在1—100 nm 之间, 处于原子簇和宏观物体交界的过渡区域, 是一种典型的介观系统。它所具有 的体积效应、表面效应、量子尺寸效应和宏观量子隧道效应使得纳米固体材料在力学、电学、磁学、热学、光学和化学活性等方面具有奇特的性能, 因而在许多方面有着广阔的应用前景。 复合材料可以通过不同质的组成、不同相的结构、不同含量及不同方式的复合而制备出来, 以满足各种用途的需要。其综合性能远优于各单组元, 并且可以具有单组元所不具备的新性质。新型多功能复合材料是一个举世瞩目的特殊的研究和发展领域, 它对科学技术的发展有着重要的意义。目前世界各国科技人员对纳米复合材料颇感兴趣,研究极为活跃。本文将从材料制备、性能和应用等方面着重介绍无机?有机纳米复合材料的研究进展。 HA:羟磷灰石.粉末. 　羟基磷灰石，又称羟磷灰石，是钙磷