01-流变学基础研究.ppt

* * * Recoverable component * There are fundamentally two parts of the oscillation that we can control. The oscillation AMPLITUDE, stress or strain. Run an amplitude sweep experiment to determine the Linear Viscoelastic Region. The oscillation timescale / FREQUENCY. Run an frequency sweep experiment to determine the response for different timescales. * Indicates the stability of a suspension As the storage modulus does not change we know this is non-destructive to the material. Any subsequence tests are kept within the LVR Can calculate the “Cohesive Energy” to quantify stability. How much energy required to break suspension. The larger, the more stable. * * * CASE STUDY: Play Putty - Freq. Sweep * * Material Behaviour Three general material behaviours. Material property at rest (0Hz) classifies behaviour. * * Frequency sweep - liquid soaps Viscosity and modulus can be the same. Good sample is elastic, solid like – snaps. Bad sample is viscous liquid like – strings. * Time Sweep – Glue Curing Characterises how a glue sticks. Viscously dominated at the beginning – easy to apply. Elastically dominated at the end to bond strongly. * Temperature sweep – Butter Butter melts as it gets hotter – it melts, viscosity lowers. Different peaks in phase angles – different fat components. * * 根据Winter的定义，不同频率下，损耗角正切曲线的交点就是凝胶点。 Basic sine at 0.1 Hz with harmonics up to 30 Hz Exact determination of Gelpoint according to Winter’s definition * Asphalt performance * * * * * * Isothermal, stationary Flow of an incompressible fluid * * * What happens to hand cream SAMPLE STORAGE Very low shear rates: ~ 0.001s-1 How stable is it, sample quality… SAMPLE DELIVERY Medium shear rates: ~10s-1 Pumpability? Scoopability? SAMPLE APPLICATION 1 Low shear rates: ~1s-1 Flows away? Flows off hand SAMPLE APPLICATION - 2 Higher shear rates: ~100s-1 Too thick to spread? Nice feel? * * This structure is now so strong that a low shear rates, the viscosity is infinite – it doesn’t flow!