中空纳米粒子的合成总结.ppt

Theoretical Considerations The initial stage is the generation of small Kirkendall voids intersecting the product interface via a bulk diffusion process (Figure2b); The second stage is dominated by surface diffusion of the core material (viz., the fast-diffusing species) along the pore surface (Figure 2c). 活化能Q：体积扩散晶粒间界扩散表面扩散 活化能Q小，扩散系数大 Theoretical Considerations Example：Voids at planar substrates based on the Kirkendall effect. a) Deposition of vapor Pt on an Al substrate, forming an amorphous alloy layer. b) Solid-solid reaction between ZnO substrate and a thin alumi