智能窗的热致变色VO2薄膜论述.pptVIP

Thermochromic VO2 thin film for smart window Y.J.Zhou Table of contents Working principle VO2 undergoes reversible transition at critical temperature Tc (68℃) ; below 68℃ ，VO2 is semiconducting and relatively infrared transparent,and above Tc it is metallic and infrared reflecting.(NIR:0.78-2.5um) Methods of synthesis Sol-gel method Chemical vapor deposition DC、RFmagnetron sputtering Pluse laser deposition Sol-gel method Merits of Sol-gel method Chemical vapor deposition Problems God is impartial , who endows a kind of material with outstanding properties wh- ile in turn hard to prepare. * Y.C.Zhou T.Y.Zhou J.Q.zheng 1 Introduction 2 Methods of synthesis 3 Problems Solutions Winter Summer To outside From outside Window 58% Window 73% Floor 7% Floor 3% Roof 5% Roof 11% Wall15% Ventilation 15% Wall 7% Ventilation 6% Resistance of a suspended VO2 nanobeam measured in a four-probe geometry as a function of temperature [1] [1] Jinqian Wu,Qian Gu , Nanoletter,2006 Vol.6,No.10,2313-2317. [2] Litao Kang,?,? Yanfeng Gao, ACS,Applied material interfaces, VOL. 1 ? NO. 10 ? 2211–2218 ? 2009 Optical transmittance spectra of VO2 film [2] ★ ★ Mixing solution (HCl,N2H4,V2O5) Sol (Only VOCl2) Gel AddingPVP Adjust pH Primary product Spin coating [5] Litao Kang,Yanfeng Gao,J.Phys.Chem.C ,2010,114,1901-1911 Second product Drying Final product Annealing Without PVP PVP Low cost Sol-gel Easyhandling Ease fordoping Large scaleprocess Vaporization and Transport of Precursor Molecules into Reactor Adsorption of Precursor Molecules to Surface Decomposition of Precursor Molecules on Surface and Incorporation into Solid Films Recombination of Molecular Byproducts and Desorption into Gas Phase Diffusion of Precursor Molecules to Surface Uniformity Repeativity Large scale Film thickness control Good substrate adhesion CVD Applications ??? Q1:High MIPT temperature (≈68℃) Q2:L