燃烧理论_2燃烧与热化学解答.ppt

* * Gas-Gas Heat Exchanger * 烧嘴A 烧嘴B 交替切换 steel Nox emission fuel fuel 陶瓷球型蓄热体 gas air gas 切换阀 1620 K Preheated air 1270 K 分散式余热回收方式 出处：NKK公司（日本）：“蓄热式烧嘴加热炉概要及其在钢铁设备上的应用” Basic conception * 25-30% 以往的水平 预热前窑炉出口排烟温度 ℃ 1400 1200 1000 800 600 400 50-60% 70 60 50 40 30 20 10 0 0 200 400 600 800 1000 1200 1400 预热空气温度 燃料节约率 % ℃ 出处：NFK公司（日本 ：产品目录 节能潜力 * 例 2.8 图2.16所示的一个对流换热式回热器，用于天然气加热的热处理炉上. 炉在常压下工作，当量比为 0.9. 燃料气的入口温度为298K, 空气被预热 A.求当空气预热温度从298K到1000K时对绝热火焰温度的影响. B. 空气温从298K 升到600K时的节能有多少?假设不管是预热还是不预热空气，炉子的出口 进入换热器前）烟气温度1700K。 * 解 Part A Fortran program HPFLAME, which incorporates the Olikara and Borman equilibrium routine, to solve the first-law problem, Hreac Hprod. The input file for the program requires the definition of the fuel by providing the number of carbon, hydrogen, oxygen, and nitrogen atoms constituting the fuel molecule, the equivalence ratio, a guess for the adiabatic flame temperature, the pressure, and the reactants’ enthalpy. * The input file for this example, treating natural gas as methane, is shown below: Adiabatic Flame Calculation for Specified Fuel, Phi, P, Reactant Enthalpy Using Olikara Borman Equilibrium Routines * Problem Title: Example 2.8 Air Preheat at 1000K 01 /Carbon Atoms in fuel 04 /Hydrogen atoms in fuel 00 /Oxygen atoms in fuel 00 /Nitrogen atoms in fuel 0.900/Equivalence ratio 2000./Temperature K Initail Guess 101325.0 /pressure Pa 155037.0 /Enthalpy of reactants per kmol fuel kJ/kmol-fuel * The only quantity requiring calculation is the reactants’ enthalpy, expressed as kJ/kmol of fuel. To find the number of moles of O2 and N2 supplied per mole of fuel, we write our combustion equation as * Where Thus, The reactants’ enthalpy per mole of fuel is then * The above expression can be evaluated for various temperatures * 空气温度增加100K，烟气温度增加50K，原因： 1、分解？ 2、烟气比热比空气大？ 事实：烟气量比空气量大 * * Solution part B To determine the amount of fuel saved as a result of preheating the air to 600K, we will write an energy balance fo