活性自由基聚合,ATRP研究进展研讨.ppt

Atom Transfer Radical Polymerization (ATRP);Developed in 1995：;Developed in 1995：;Results of ATRP:;Results of ATRP:;Results of ATRP:;Results of ATRP:;Results of ATRP:;Atom Transfer Radical Addition (ATRA);;Mechanism of ATRP:;OTSU曾经的工作:;;平衡的建立： persistent radical effect;平衡的建立： 只需要很短的时间，双基终止占大分子的比例一般低于5%。;; Kinetics of ATRP:;;Keq的大与小对聚合的影响分析: 聚合速率和可控性, Keq大时聚合速率不一定快。;Keq（KATRP)影响因素：;;;死链的比例;适宜进行 ATRP的单体:;;;; 不适用于ATRP的单体:;ATRP的引发剂:;ATRP的引发剂:;;;;官能化引发剂：;;ATRP的催化剂;ATRP的催化剂; CuX的配位剂:;;ATRP的催化剂;;;;Rule of Cu(0):;反ATRP机理:;反ATRP：;反ATRP机理:;simultaneous reverse and normal initiation (SRNI);;嵌段共聚物合成中的嵌段顺序问题：;模型化合物研究:;;溴-氯原子交换：;嵌段共聚物的合成:;嵌段共聚物的嵌段顺序:;双官能引发剂：;C6H5CHBr2, 苯乙烯ATRP的双官能引发剂:;;嵌段共聚物合成：;嵌段共聚物合成;;;;;;梯度共聚物;大分子单体合成;;;Macromolecules 2001, 34, 4375-4383;;接枝共聚物合成;接枝共聚物合成;;;;;超枝化聚合物的合成:;;星形聚合物的合成:;星形聚合物的合成:;;末端官能化;端功能基聚合物;功能引发剂:;simultaneous reverse and normal initiation (SRNI);Initiators for continuous activator regeneration(ICAR) ATRP;Initiators for continuous activator regeneration(ICAR) ATRP;Activators generated by electron transfer (AGET) ATRP;;Activators regenerated by electron transfer(ARGET) ATRP;;ATRP中可能发生的副反应：;ATRP中可能发生的副反应：;ATRP催化剂的脱除：;ATRP催化剂的脱除：;;;;稳态与平衡：;;The first ITP-derived fluoroelastomers were commercialized by Daikin (then by its subsidiary Dai-Act) under the range Dai-El.;;;;;;PVC的结果：;SET-LRP 机理：;Ultrafast Polymerization at Room Temperature the total surface area of Cu（0） was increased through variation of Cu particle size, or through the use of extended Cu wire sources in the SET-LRP of MA, have shown that nearly complete conversion can be achieved in under 15 min, while maintaining similar levels of living character and perfect chain-end functionality. ;Perfect Retention of Chain-End Functionality Colorless Reaction Mixtures and Colorless Polymers simple and easily recoverable and recyclable Cu(0)catalysts, compatibility with a diverse array of solvents including “green”and aqueous solvents 。 ;;;;;;;;;;;