通过表面反应和沉积合成无机纳米空心球课程方案.ppt

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2016-07-22 发布于湖北
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通过表面反应和沉积合成无机纳米空心球课程方案.ppt

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Synthesisofinorganicnano-hollowspheresbysurfacereactionanddepositionGroupNO.4Reporter：邹冀Othermembers：诸葛福伟周健王焕磊吕勇OutlineFundamentalconceptsGeneralsynthesismethodofcore-shellparticlesSurfacechemicalreactionanddeposition(Hollowoxide,nitride,carbide,boridespheres)FocusofcurrentresearchWhatisacore-shellstructure?ConsistofeitherorganicorinorganiccoreandcoatedwithshellsSelectivedissolutionorcalcinationstoobtainahollowsphereWhatspecialpropertiescouldbeobserved?DifferentsurfacechemicalcompositionIncreasedstabilityHighersurfaceareaMagneticandopticalpropertiesFundamentalconceptsWhatisitfor?Duetoitsspecialstructureandattractivefunctionalfeatures,itcouldbeusedin:Catalysis,coatingsCapsuleagentfordrugdeliveryProtectionforsensitiveagent(enzyme..)Electro-opticcrystalAndsoon….FundamentalconceptsSynthesismethodsChemicalmethodsTemplatemethodTemplateandlayer-by-layermethod(LBL)Surfacechemicalreactionanddeposition(SCRD)KirkendalleffectTemplatefreemethodInside-outOstwaldripeningmechanism.Solvent-thermalSynthesisPhysicalmethodsSpray-dryingmethodsLiquidDropletMethod(1)hardtemplateOrganicpolymerbeads(PSPMMAPVC…….)Inorganicnano-particles(CaCO3Fe3O4SiO2C……)Metallicnano-particles(2)softtemplateMicelles(EBE,EPE)GasVesicles(liposome)(morpesis,transcripitysynthesis)TemplatesMechanism(1)Layer-by-Layer(LbL)ElectrostaticbetweenchargedspeciesDepositioncyclesMechanism(2)Surfacereactionanddeposition(SCRD)DesignorfindoutthereactionsystemandprocedureStep1:synthesisoforgano-mineralseedlatexparticlesStep2:growthreactionofteraalkoxysilaneontotheseedlatexparticlesHollowoxidespheres(1)HybridLatexParticlesCoatedwithSilicaTissotIMacromolecules2001Scalebar:100nm.PS-MPS@SiO2PS@SiO2ThemainresultsASteptowardtheSynthesisofHollowSilicaNanoparticlesTissotIChem.Mater.2002,14,1325-1331Hollowoxidespheres(2)FurtherunderstandingofthereactionsystemHollowoxidespheres(3)Amistakeandcorrection?Theformationofcore-shellhybridspheres(1)(2)(3)ChenywAdvancedfunctionalmaterials.200515NO.1Justasimilarresults?VBCHollowoxidespheres(4)On