通过表面反应和沉积合成无机纳米空心球.ppt

Synthesis of inorganic nano-hollow spheres by surface reaction and deposition;Outline;What is a core-shell structure? Consist of either organic or inorganic core and coated with shells Selective dissolution or calcinations to obtain a hollow sphere What special properties could be observed? Different surface chemical composition Increased stability Higher surface area Magnetic and optical properties;What is it for? Due to its special structure and attractive functional features, it could be used in: Catalysis, coatings Capsule agent for drug delivery Protection for sensitive agent (enzyme..) Electro-optic crystal And so on….;Synthesis methods;(1)hard template Organic polymer beads (PS PMMA PVC …….) Inorganic nano-particles (CaCO3 Fe3O4 SiO2 C……) Metallic nano-particles (2)soft template Micelles (EBE, EPE) Gas Vesicles(liposome) (morpesis,transcripity synthesis) ;Mechanism (1);Mechanism (2);Hollow oxide spheres(1);Scale bar: 100 nm.;A Step towardthe Synthesis of Hollow Silica Nanoparticles;Further understanding of the reaction system;The formation of core-shell hybrid spheres ; ;One-step process;Xiaoming Sun and Yadong Li Angew. Chem. Int. Ed. 2004, 43, 597 –601;How does the new template work?;Angew. Chem. Int. Ed. 2004, 43, 3827 –3831;Yong Zhang,Er-Wei Shi,;;Silicon carbide hollow nano-spheres ;Focus of current research;Nobel prize 2005;;Who is the next?