第三讲：反应机理讨论.ppt

反应机理讨论;d electrons in group 3 are readily removed via ionization, those in group 11 are stable and generally form part of the core electron configuration.;valence (d) electron count:;Transition Metal Valence Orbitals;Two Rules:;;Common Geometries for TM Complexes;σ and π bonding in ML6;;;配体交换（配体的配位和解离）;Trans-Effect;氧化加成与还原消除(Oxidative Addition/Reductive Elimination);;;OA: Concerted 3-centered (non-polar substrates);Dihydrogen σ-complexes;Dihydrogen σ-complexes;Hydrogenation (氢化);Wilkinson hydrogenation: classic dihydride mechanism;The ‘Holy Grail’ of Catalysis;C-H Activation: sp3C-H σ comp