清华大学李艳梅有机化学课件第四章-环烷烃预案.pptVIP

Cycloalkanes 第四章 环烷烃;Content; 4.1 Classification, Isomerization and nomenclature;4.1.1 Classification;;To define the number of the rings: The number of cutting you need to get a chain molecule out of a poly ring compound;Some interesting bridging compounds;4.1.2 Isomerism ;4.1.3 Nomenclature 命名;2, When the side chain is complicate or difficult to name: 当支链较复杂或不易命名时，以环烷基为取代基;4, Cis and trans isomerism:;How to name this compound ?;4.1.3.2 Polyring alkane 多环烷烃;“小原则”：在不违背螺环烃命名的“大”原则基础上，在编号时应尽可能令取代基的位号最小。;spiro[4.5]decane 螺[4.5]癸烷;1）选母体：根据成环的总碳原子数及环数，称为“n环某烷”。 2）编号：