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Heavy metal removal and speciation transformation through thecalcination treatment of phosphorus-enriched sewage sludge ash
通过煅烧处理富含磷的污水污泥灰去除重金属及转变其形态
College of Energy and Environment, Shenyang Aerospace University, The Key Laboratory of Clean Energy in Liaoning Province, Shenyang, China
Journal of Hazardous Materials 工程类1区文献
Abstract
On the basis of the heavy metal (Cd, As, Pb, Zn, Cu, Cr, and Ni) control sewage sludge (SS), P-enriched sewage sludge ash (PSSA) was calcined at 1100 ?C. The effect of organic chlorinating agent (PVC) and inorganic chlorinating agent (MgCl2) onthe ?xed rate of P removal and the speciation transformation of heavy metal was studied.
Introduction
Phosphorus (P) is an essential element for biological growth and is a non-renewable resource. The world has limited phosphate resources, with forecast reserves maintained for less than 100 years. Phosphate has been listed among the 20 minerals that cannotmeet the demand of national economic growth in China .
Materials and methods
BCR三态模拟法
Fraction 1, acid soluble
Fraction 2, reducible
Fraction 3, oxidizable
Fraction 4, residual
Results and discussion
PVC:Cu zn Pb As ≈ Cr Cd NiMgCl2 :Cu Zn Pb Cr Ni As Cd
Effect of chlorinating agent
Conclusion
This ?nding is bene?cial for the environment
and presents an effective method for PSSA recycling.
thank you
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