参考资料--环保型三价铬电镀工艺研究.docVIP

环保型三价铬电镀工艺研究 摘要：目前，三价铬电镀工艺己经成为取代重污染六价铬电镀的最重要技术之一。对三价铬电镀工艺进行深入研究并使其在实际生产中得到大规模推广应用，对突破国外技术壁垒、实现我国电镀行业的清洁生产等都具有极其重要的现实和战略意义。 本论文从三价铬电镀工艺的三大技术难题出发，分别对硫酸盐体系和氯化物体系三价铬电镀装饰铬工艺进行了深入研究。通过Hull槽试验、小槽挂镀试验和放大试验，制备出硫酸盐体系三价铬电镀所用DSA阳极和氯化物体系三价铬电镀所用石墨阳极，确定出两种体系的全套工艺规范，并对阴阳极反应机理进行了详细探讨。 关键词： 三价铬电镀硫酸盐体系氯化物体系DSA阳极 Study on Trivalent Chromium Electroplating Process of Environmental Protection Abstract At present，trivflem chromium elec自roplating process has became one of the mostimportant techniques to taking place of the seriously pollutional hexvalent chromiumelectroplating process．Studing deeply on the trivalent chromium electroplatingprocess，mading it apply on mass production has highly realistic and strategicalsignificance to breaking through the overseas technical barrier and achieving the goal of Clean Production in Chinese electroplating industry．Starting from the three big technical problems in the trivalent chromium electroplating process，a deep study had been made on the ornamental trivalent chromium electroplating process in sulpbate system and chloride system in this dissertation．With the methods of Hull cell testing，small size cell rack-plating testing and scale—up experiment testing and SO on,we made the Dimensionally Stable Anode for砸valem chromium electroplating in sulphate system and graphite anode in chloride system,and entire process criterions for the two systems．At the same time，a detailed discussion had been conducted on the reaction mechanism of the anode and cathode in this dissertation．The process standards were showed as follow： The measuring results indicated that,self-made Dimensionally Stable Anode had high electrocatalytic activity for oxygen evolution,and good conductivity else．Thisanode had favorable capability to restraining C，creation．There was no serious problems such弱C，creation or chlorine evolution in self-made products of the twosystems at the period of electroplating．The integrative performance of the self-made products had reached the same level of