高性能有机纤维增强合材料的界面性能研究.docxVIP

高性能有机纤维增强复合材料的界面性能研究 201001130606 高同舜 高性能有机纤维增强复合材料的界面性能研究 摘要：为了改善超高分子量聚乙烯(UHMWPE)纤维、芳纶纤维增强树脂基复合材料的界面粘结性能，本文从树脂基体入手，依据相似相容原理和纤维的结构特点开发出两种新型热固性树脂—PCH 树脂和 AFR 树脂，分别用作 UHMWPE 纤维复合材料和芳纶复合材料的基体，以未经表面处理的纤维作增强材料，采用热压成型法制备了 UHMWPE 纤维/PCH 和芳纶/AFR 复合材料，并通过测定接触角、层间剪切强度(ILSS)、横向拉伸强度和扫描电镜观察形貌等方法研究了复合材料的界面粘结性能。结果表明：UHMWPE 纤维和 PCH 树脂浇注体的溶度参数相近，PCH 树脂溶液在 UHMWPE 纤维表面的接触角为 15.6°，说明对其具有良好的浸润性；UHMWPE/PCH 复合材料的 ILSS 和单丝拔出强度分别为 42.6MPa 和 21.8MPa，均远大于 UHMWPE/环氧树脂(EP)复合材料的相应强度，扫描电镜分析也表明 UHMWPE 纤维增强 PCH树脂基复合材料具有优异的界面粘结性能。AFR 树脂溶液与芳纶纤维的接触角为 42.8°，而 EP 与芳纶的接触角为 68°，说明 AFR 树脂对芳纶的润湿性优于 EP；芳纶/AFR 复合材料的 ILSS、横向拉伸强度和纵向拉伸强度分别为 74.6MPa、25.3MPa、2256 MPa，比芳纶/EP 复合材 料的相应强度分别提高了 28.7%、32.5%和 13.4%，其复合材料破坏面的形貌也说明芳纶与 AFR 树脂之间的界面粘结性能较好。 Abstract: In order to improve the interfacial adhesion of UHMWPE fiber and aramid fiber reinforced polymer matrix composites, two new thermosetting resin systems (PCH and AFR) have been developed according to law of similar mutual solubility and the structural characteristics of fibers. The adhesion properties of UHMWPE fiber/PCH and aramid /AFR composites were investigated by the methods of the contact angle, interlaminar shear strength, transverse tensile strength and scanning electron croscopy etc. Test results show that a strong interaction occurs between fibers and the matrix due to the structural and polar similarity. In the case of slight ifference between solubility parameters of UHMWPE fiber and cured PCH resin, it is found that the wettability of PCH resin on surface of the fiber can be improved and UHMWPE /PCH composite has excellent transverse tensile strength, interlaminar shear strength and the pull-out strength together with the outstanding interfacial bond property. The contact angle (42.8 °) between AFR resin and aramid fiber is smaller than the contact angle (68°) between the epoxy resin (EP) and aramid fibers. Therefore, the AFR resin had better wettability with the aramid fibers. The nterlaminar shear strength, tra