董春燕论文稿.docVIP

聚合硅酸硫酸铝絮凝剂的制备及应用 摘 要 聚合硅酸硫酸铝（PSAS）是为克服聚合硫酸铝的贮存不稳定性，将硅引入其中而形成的一种新型高分子无机聚合物。它保持了聚合硫酸铝易水解、脱稳性好等优点，并且处理后的水中Al3+残留量低且储存稳定性好，易于商品化。其中SO42-来源广泛，可被生物完全降解，对环境无副作用，是一种高效絮凝剂。 实验采用复合法制备PSAS是将硫酸铝引入到聚硅酸当中，同时添加稳定剂。采用的是常温慢速滴定法:将不同A13+/Si摩尔比的硫酸铝溶液滴入聚硅酸中，添加微量的稳定剂，快速搅拌2min后，测量混合液的pH值；然后将1mol/L NaOH溶液滴定到混合液中，得到所要的碱化度B；在滴定NaOH溶液过程中记录整个的pH变化，快速搅拌以保证得到均匀的溶液；最后将混合液密封，在恒温水浴中使其熟化一段时间，即得不同A13+/Si摩尔比、不同碱化度B的聚合硅酸硫酸铝产品(PSAS)。 实验考察了硅酸钠的活化pH值、SiO2含量以及温度对聚硅酸合成的影响；考察了原料硫酸铝与硅酸钠的A13+/Si摩尔比、碱化度B、聚合时间对PSAS的絮凝效果的影响。实验结果表明：SiO2的含量：2%–3%；硅酸活化pH值为：5.0左右；硅酸的聚合时间为：25min左右；硅酸的聚合温度约：20±5℃；就絮凝效果而言，铝硅比1.0，碱化度2.0，聚合时间为10d对废水的除浊效果最佳。 关键词：聚合硅酸硫酸铝 絮凝剂 合成 絮凝机理 Preparation and Application of Poly-silicate Aluminum Sulfate(PSAS) Abstract Poly-silicate Aluminum Sulfate(PSAS) is?polymerization?to overcome the instability of?aluminum sulfate?storage?into?which?the silicon?to form?a new polymer?inorganic?polymers. It?is easy?to maintain?the polymerization?of aluminum?sulfate?hydrolysis, destabilization?and good benefits, and?Al3+?in water?treatment?residues and?low?storage stability, and easy to?commercialization. SO42-wide variety of sources?which?can?be?completely?bio-degradable no side effects?on the environment,?is a highly effective?flocculant. Experiments using compounding method preparation of PSAS was to add A12(S04)3 to Poly-silicic acid, add stabilizer .At normal temperature slow titration :different A13+/Si molar ratio of aluminum sulfate solution instillation of Poly-silicic acid, add a small amount of stabilizer, rapid mixing 2 min, the measurement of the mixure of pH value; then 1mol/L NaOH solution titrated to the mixture to obtain the desired basicity B; record the pH change in the titration of the NaOH solution process, quickly stir in order to ensure a uniform soiution; finally, the mixture sealed in a constant temperature water bath so that ripening period of time, i.e. Poly-silicate Aluminum Sulfate products of different A13+/Si molar ratio, different basicity B( The PSAS). This paper ex