扫描探针显微镜及其应用解决方案.ppt

前景展望 Fc (o) + Fe(CN)63- (w) = Fc+ (o) + Fe(CN)64- Figure Experimental approach curves (dot) fitted with theoretical values (line). The DCE phase contained 0.01M TBATPBCl and 0.2mM ferrocene. The aqueous phase contained 0.1M LiCl + xM K3Fe(CN)6 + yM K4Fe(CN)6. (D)x = y = 0.2mM. From top to bottom, the external-potential were -0.10V, -0.05V, 0V, 0.05V, 0.10V, 0.20V and 0.30V. All of the approach rates were 1μm/s. Investigation of Modified Electrodes Surface pKa Figure: Schematic diagram of the application of SECM to probe facilitated ion transfer at an externally polarized Liquid/Liquid interface Probing facilitated ion transfer at an externally polarized L/L interface Study of simple ion, facilitated ion and electron transfer across a liquid/liquid interface by three-electrode system Figure: Cyclic voltammograms obtained for charge transfer reactions by use of a three-electrode setup (a) Potential window and facilitated K+ transfer reaction, the cell is: Ag/AgTPBCl/10mM TBATPBCl + 0.25 mM DB18C6)//100mM KCl/AgCl/Ag (b)??(b) Potential window and electron transfer reaction, the cell is: Ag/AgTPBCl/10mM TBATPBCl + 0.2mM TCNQ)//1M LiCl + 10 mM K3Fe(CN)6 + 400 mM K4Fe(CN)6 /AgCl/Ag (c)??(c) Potential window and TEA+ transfer reaction, the cell is: Ag/AgTPBCl/10mM TBATPBCl //100mM LiCl + 0.4m M TEACl /AgCl/Ag Figure: Experimental approach curves of a 238-nm-radius pipet fitted with the theoretical values. The tip potential is 0.45V, the substrate potential is(■) 0.20V (╳)0.225V (□)0.25V(▲) 0.275V (*)0.30V (О)0.325V (●)0.35V(△)0.375V(◇) 0.40V (◆) 0.425v (––)curve 1 theoretical curve for diffusion controlled process, curves 2-6 theoretical curves for kinetics controlled process. The inset shows dependence of the heterogeneous rate constants on different Es- Eso’. Angew. Chem. Int. Ed. 2002, 41, No. 18, 3445-3448 Approaches to Imaging Biological and Biochemical Systems A. Negative Feedback Imaging B. Non-Specific Positive Feedback Imaging